This paper assesses the suitability of geopolymers (GPs) for use as adhesives for ceramic tile fixing, including their compliance to relevant EN 12004 specifications. Two series prepared with different percentages of metakaolin (MK), blast furnace slag (BFS), and limestone materials activated by an alkaline NaOH/Na2SiO3 solution are investigated. Tested properties included the thixotropy, setting, compressive strength, open time, and adhesion bond strength under different exposure conditions (i.e., dry, wet, heat, or freeze/thaw cycles). Compared to cement-based mortars containing adjusted proportions of cellulose and redispersible polymers, the GPs exhibited higher thixotropy reflecting additional energy for spreading the material over the substrate, yet better maintaining of the alternating patterns of ripples and grooves at rest. The bond strengths tested under different exposure conditions were remarkably high for the MK-based GP, given the fine MK particle sizes that foster geopolymerization and cross-linking of solid bonds in the hardened structure. The BFS-based GP exhibited relatively lower bond strengths (compared to MK) due to coarser particles. Such results can be of interest to civil engineers and manufacturers of ready-to-use building materials that aim at reducing the Portland cement footprint while assuring the performance and sustainability of tiling applications.

The use of recycled concrete aggregates (RCAs) in lieu of natural aggregates improves the sustainability of the built environment. Barriers to the use of RCA include its variable composition, including the residual mortar content (RMC), chemical composition, and its potential to contain contaminants, which can negatively affect the properties of concrete or present environmental concerns. In this study, a rapid, economical method to estimate the RMC and provide the chemical characterization of RCA was developed using a portable handheld X-ray fluorescence (PHXRF) device. Models were developed using reference tests (RMC test based on the thermal shock method and chemical composition from whole-rock analysis) to correlate PHXRF results to measured values. The PHXRF shows strong potential for estimating the RMC and chemical composition of RCA. Paired with locally calibrated reference samples, the test method could be used in laboratory or field applications to characterize RCA and increase its use in bound and unbound applications.

A requirement for achieving sustainable concrete structures is to develop a quantitative method for designing concrete mixtures that yields the target rheological properties and compressive strength. Toward this objective, this paper proposes a mathematical model approach to improve the sustainability of the concrete industry. A postulation that packing density, a function of the concrete mixture, provides the link between concrete mixture, rheological properties, and compressive strength was investigated. Rheological models for yield stress and plastic viscosity, and a compressive strength model were adopted with packing density as a central variable. The rheological models employ a cell description that is representative of fresh concrete. The compressive strength model is based on excess paste theory to account for the concrete mixture proportions, gradation of aggregate particles, and porosity. An experimental program was developed to calibrate and test these models. Results revealed that packing density provides a consistent and reliable link, and that the concrete mixture composition can be designed to achieve the target rheological properties and hardened properties and ensure quality control. Consequently, a new mixture proportioning methodology was developed and proposed as an improvement to the ACI 211.1 mixture design method. Furthermore, a case study was conducted to test for the applicability and adequacy of this proposed method. This research outcome, which provides a quantitative approach to design concrete mixtures to meet specific strength requirements and rheology, can also be used to ensure quality control before concrete is cast.

The overdesign of concrete mixtures and substandard concrete acceptance testing practices significantly impact the concrete industry’s role in sustainable construction. This study evaluates the impact of overdesign on the sustainability of concrete and embodied carbon emissions at the national and project scales. In addition, this paper reviews quality results from a concrete producer survey; established industry standards and their role in acceptance testing in the building codes; the reliance on proper acceptance testing by the licensed design professional, building code official, and the project owner; and the carbon footprints that result from overdesign of concrete mixtures. In 2020, a field survey conducted on over 100 projects documented Pennsylvania’s quality of field testing. Of those surveyed, only 15% of the projects met the testing criteria within the ASTM and building code requirements. As a result, the total overdesign-induced cement consumption is as large as 6.7% of the estimated cement used in the United States.

An important part of improving the embodied carbon of the built environment is reducing carbon emissions associated with concrete. The long-term limitations around the availability of supplementary cementitious materials (SCMs) to replace portland cement have driven the search for additional innovative approaches. The beneficial use of carbon dioxide (CO2) in ready mixed concrete production has been developed and installed as retrofit technology with industrial users. An optimum dose of CO2 added to concrete as an admixture leads to the in-place formation of mineralized calcium carbonate (CaCO3) and can increase the concrete compressive strength. The improved performance can be leveraged to design concrete mixture proportions for a more efficient use of portland cement, along with the use of CO2 to reduce the carbon footprint of concrete. One producer has used the technology, starting in 2016, at over 50 plants. More than 3 million m3 of concrete have been shipped with an estimated net savings of 35,000 tonnes of CO2. The concrete produced with carbon dioxide is discussed in terms of the fresh and hardened performance, durability performance, and life cycle impacts.