Self-healing is a process by which concrete is able to recover its properties after the appearance of cracks, which can improve mechanical properties and durability and reduce the permeability of concrete. Self-healing materials can be incorporated into concrete to contribute to crack closure. This study aims to evaluate the influence of crystalline admixtures and silica fume on the self-healing of concrete cracks. The rapid chloride penetration test was performed on cracked and uncracked samples, from which it was possible to estimate the service life of concretes. The concretes were characterized by tests of compressive strength and water absorption by capillarity. The use of crystalline admixtures did not have a negative influence on concrete properties, but did not favor the chloride penetration resistance. The concrete with silica fume showed the lowest charge passed and highest values of estimated service life.

The built environment is facing an increasing challenge of reducing emissions regarding both embodied and operational carbon. As an ultra-durable concrete, engineered cementitious composites (ECC) reduce the need for repair, thus resulting in a prominent reduction of life-cycle footprints. Herein, a new version of low-carbon ECC was developed for cast-in-place applications by sequestering CO2 through mineralization. Two waste streams were pre-carbonated and incorporated into ECC as fine aggregate and supplementary cementitious material, respectively. At 28 days, the CO2-sequestered ECC exhibited a compressive strength of 32.2 MPa (4670 psi), tensile strength of 3.5 MPa (508 psi), and strain capacity of 2.9%. Multiple fine cracks were distinctly identified, with a residual crack width of 38 μm (0.0015 in.) and a selfhealing behavior comparable to that of conventional ECC. The new ECC sequestered 97.7 kg/m3 (164.7 lb/yd3) CO2 (equivalent to 4.7 wt% of final mixture) and demonstrated a 42% reduction in cradle-to-gate emissions compared to conventional concrete at the same strength level. This study demonstrates the viability of turning waste CO2 gas into durable construction materials and proposes a potential path towards carbon neutrality.

This research focuses on the evaluation of the sustainability of recycled ultra-high-performance concrete (R-UHPC) in a life cycle analysis (LCA) perspective, and with reference to a case study example dealing with structures exposed to extremely aggressive environments. This involves the assessment of the self-healing capacity of R-UHPC, as guaranteed by the R-UHPC aggregates themselves. Recycled aggregates (RA) were created by crushing 4-month-old UHPC specimens with an average compressive strength of 150 MPa. Different fractions of recycled aggregates (0 to 2 mm) and two different percentages (50 and 100%) were used as a substitute for natural aggregates in the production of R-UHPC. Notched beam specimens were pre-cracked to 150 μm using a three-point flexural test. The autogenous self-healing potential of R-UHPC, stimulated by the addition of a crystalline admixture, was explored using water absorption tests and microscopic crack healing at a pre-determined time (0 days, 1 month, 3 months, and 6 months) following pre-cracking. Continuous wet/ dry healing conditions were maintained throughout the experimental campaign. The specimens using R-UHPC aggregates demonstrated improved self-healing properties to those containing natural aggregates, especially from the second to the sixth month. To address the potential environmental benefits of this novel material in comparison to the conventional ones, an LCA analysis was conducted adopting the 10 CML-IA baseline impact categories, together with a life cycle cost (LCC) analysis to determine the related economic viability. Both LCA and LCC methodologies are integrated into a holistic design approach to address not only the sustainability concerns but also to promote the spread of innovative solutions for the concrete construction industry. As a case study unit, a basin for collection and cooling of geothermal waters was selected. This is representative of both the possibility offered, in terms of structural design optimization and reduction of resource consumption, and of reduced maintenance guaranteed by the retained mechanical performance and durability realized by the self-healing capacity of R-UHPC.

The main focus of the current research is the development of high-performance fiber-reinforced cementitious composites with large amounts of coarse aggregates without risking deflection-hardening response, and the evaluation of the autogenous self-healing capability of these composites at different scales. The structural performance of cementitious composites exhibiting strain hardening should be known to be used in large-scale specimens. In addition to the studies carried out in small sizes, there is a need to examine the self-healing performances of large-scale specimens. Composite mixtures included different design parameters—namely Class F fly ash-to-portland cement ratio (FA/PC = 0.20, 0.70), aggregate-cementitious materials ratio (A/CM = 1.0, 2.0), addition/type of different fibers (for example, polyvinyl alcohol [P], nylon [N], and hooked-end steel [S] fibers), addition/type of nanomaterials (for example, nanosilica [NS] and nanoalumina [NA]) and inclusion of steel reinforcing bar in tested beams. Small-scale (80 x 75 x 400 mm [3.15 x 2.96 x 15.76 in.]) and large-scale beams (100 x 150 x 1000 mm [3.94 x 5.91 x 39.4 in.]) were produced and considered for performance comparison. Four-point bending tests were performed on different-scale beams loaded by considering different shear span-effective depth ratios (a/d) ranging between 0.67 and 2.00 and 0.67 and 2.96 for small- and large-scale beams, respectively. Autogenous self-healing evaluation was made using different-scale beam specimens subjected to 30-day further cyclic wetting-and-drying curing in terms of changes in microcrack characteristics and recovery in flexural parameters of preloaded beams. Experimental results showed that it is possible to successfully produce concrete with large amounts of coarse aggregates without jeopardizing the deflection-hardening response both at small and large scale. Autogenous self-healing is valid for small- and large-scale beams in terms of crack characteristics/flexural parameters and is found to improve with the increased FA/PC, decreased A/CM, in the presence of nanomaterials, and with the increased fiber amount (regardless of the type). Outcomes of this research are thought to be important because they show the manufacturability of deflection-hardening concrete with large amounts of coarse aggregates at large scale and validate their autogenous self-healing capabilities, which are important for the real-time applicability of such mixtures in actual field conditions.

Microbial carbonate precipitation (or biodeposition) has been widely studied for use in characteristics improvement and selfhealing of concrete and mortar of cementitious materials. The presence of a calcium source contributes to the formation of calcite (CaCO3), which is a key component in the biode-position process. The current study is aimed at benefiting from the available calcium ion in seawater as a calcium source in the biode-position of marine structures. To this end, four different bacteria strains were cultured and added to the mortar mixture for making bacteria-containing mortar specimens. The specimens consisted of six groups of 50 x 50 x 50 mm mortar cubes, 40 x 40 x 160 mm (1.57 x 1.57 x 6.3 in.) mortar prisms, and conventional mortar briquettes, all of which were cured in seawater. The effects of the exposure to seawater were mechanically investigated at different mortar ages in terms of their compressive, flexural, and tensile strengths and compared with control specimens made with no bacteria and cured in water. The experimental results represented an increase of 97% and 101%, respectively, in compressive and flexural strengths of mortar specimens containing Bacillus subtilis and cured in seawater at 28 days. It was found that the specimens cast and treated with Bacillus sphaericus exhibit a rise of approximately 72% in tensile strength. Therefore, it was concluded that treated mortar with bacteria and cured in seawater may enhance the mechanical properties of mortar, which can be a beneficial development in marine structures. The use of such bacteria strains in concrete technology, specifically in inshore structures, can eliminate the destructive effects of the coastal environment.