International Concrete Abstracts Portal

In this work, novel polycarboxylate admixtures were synthesized by two different free radical polymerization systems of methacrylic acid (MAA) and methoxy polyethylene glycol methacrylate (MPEG-MA) for PC-1, and acrylic acid (AA) and iso amyl alcohol polyethylene glycol (IAA-PEG) for PC-2. Thioglycolic acid as a chain transfer agent and ammonium persulphate as an initiator were used. The synthesized carboxylic polymers were characterized using FTIR, H-NMR, gel permeation chromatography (GPC), and thermogravimetric analysis (TGA). The influence of the chemical structure of polycarboxylates on the rheology of the concrete, as well as the prognosis of the superplasticizer’s development, is also presented through measuring water consistency, setting times, flow table, slump test, Zeta potential, and compressive strength. The cementitious products were investigated with X-ray diffraction (XRD) and scanning electron microscope (SEM). The developed superplasticizers have shown good dispersion effects and slump performance in workability and fluidity retention tests, adsorption performance, and scanning electron microscopy performance. Intriguingly, the PC-1 and PC-2 mixes achieved flow table values of 230 and 200 mm, respectively. The compressive strength values at various curing ages up to 28 days exhibited double and triple values compared with the control sample. Additionally, compared to the control ordinary Portland cement paste, a reduction of water-to-cement ratio of about 0.25 and the development of excessive hydration products give PC-1 and PC-2 extensive pastes a more dense and compact structure in XRD and SEM investigation.

The production of Ordinary Portland Cement (OPC) is a major contributor to carbon emissions. One immediate and viable solution is the use of optimized concrete mixtures that employ a decreased quantity of cement and increased dosage of high-range water-reducing (HRWR) admixtures. This study investigates five different concrete mixtures with varying w/c (0.37 to 0.42) and reduced cement contents. The mixtures with “low cement + high dosage HRWR admixture” content had over 30% increase in mechanical strength and presented 40% lower water absorption, and 68 to 97% higher formation factor, indicating enhanced durability. The optimized concrete mixtures with reduced cement and lower w/c have a service life increase of up to 117% and a life-cycle cost reduction of 29%. The application of “low cement + high dosage HRWR admixture” mixtures can improve the sustainability of concrete mixtures by reducing cement and water contents and increasing the service life of concrete in severe environments.

Crack densities obtained from on-site surveys of 74 bridge deck placements containing concrete mixtures with paste contents between 22.8% and 29.4% are evaluated. Twenty of the placements were constructed with a crack-reducing technology (shrinkage-reducing admixtures, internal curing, or fiber reinforcement) and 54 without; three of the decks with fiber reinforcement and nine of the decks without crack-reducing technologies involved poor construction practices. The results indicate that using a concrete mixture with a low paste content is the most effective way to reduce bridge deck cracking. Bridge decks with paste contents exceeding 27.3% had a significantly higher crack density than decks with lower paste contents. Crack-reducing technologies can play a role in reducing cracking in bridge decks, but they must be used in conjunction with a low paste content concrete and good construction practices to achieve minimal cracking in a deck. Failure to follow proper procedures to consolidate, finish, or cure concrete will result in bridge decks that exhibit increased cracking, even when low paste contents are used.

This study investigates the impact of under-sulfated cement combined with high-calcium fly ash and lignosulfonate-based admixtures in ready mixed concrete, leading to rapid stiffening and delayed setting. Using an on-board slump-monitoring system (SMS) installed on a ready mixed concrete truck, significant increases in water demand were recorded to maintain target slumps, with mixtures showing minimal slump response to water additions. Laboratory tests, including isothermal calorimetry and mortar trials, confirmed the under-sulfated cement’s inadequate sulfate levels as the cause. Optimal sulfate addition was determined through calorimetry, and adjustments with gypsum effectively remedied rapid stiffening and delayed setting. This research demonstrates that an SMS can detect undesirable combinations of cement, fly ash, and admixtures in concrete, allowing real-time corrections. It underscores the importance of optimized sulfate levels in cement, particularly when using high-calcium fly ash combined with some high-range water reducers, to achieve desired concrete performance under varying field conditions.

Engineered cementitious composites (ECC) represent a significantinnovation in construction materials due to their exceptionalflexibility, tensile strength, and durability, surpassing traditionalconcrete. This review systematically examines the composition,mechanical behavior, and real-world applications of ECC, with afocus on how fiber reinforcement, mineral additives, and micromechanical design improve its structural performances. The present study reports on the effects of various factors, including different types of mineral admixtures, aggregate sizes, fiber hybridization, and specimen dimensions. Key topics include ECC’s strain hardening properties, its sustainability, and its capacity to resist crack development, making it ideal for high-performance infrastructure projects. Additionally, the review discusses recentadvancements in ECC technology such as hybrid fiber reinforcementand the material’s growing use in seismic structures. The paper also addresses the primary obstacles, including high initial costs and the absence of standardized specifications, while proposing future research paths aimed at optimizing ECC’s efficiency and economic viability.