Lowering the Clinker Factor of Limestone Calcined Clay Cements (LC<sup>3</sup>) below 50%: a Comparison with Natural Pozzolans

International Concrete Abstracts Portal

The International Concrete Abstracts Portal is an ACI led collaboration with leading technical organizations from within the international concrete industry and offers the most comprehensive collection of published concrete abstracts.

  


Title: Lowering the Clinker Factor of Limestone Calcined Clay Cements (LC3) below 50%: a Comparison with Natural Pozzolans

Author(s): Franco Zunino, Karen L. Scrivener

Publication: Symposium Paper

Volume: 355

Issue:

Appears on pages(s): 81-88

Keywords: metakaolin; reactivity; clinker factor; pozzolans; sustainability

DOI: 10.14359/51736014

Date: 7/1/2022

Abstract:
The adoption of blended cements is the most feasible strategy to achieve a more sustainable industry. In this regard, reducing the clinker factor, while retaining performance, is the key parameter to address. Limestone calcined clays are a promising technology as they offer similar performance to OPC from 7 days onwards while enabling a reduction of the clinker content of 50%. In some regions of the world like South America, pozzolanic cements (i.e., blended cements that combine clinker with natural pozzolans) have been used for decades. Their clinker factors range from 80 down to 50%. However, their mechanical properties are in general lower as compared to OPC. In this study, we show that by using LC3-type formulations, cements with the same performance as commercial pozzolanic cements can be produced with clinker contents significantly below 50%. This is explained by the high reactivity of calcined clays and the synergetic reaction of metakaolin and limestone that allows offsetting the clinker reduction.

Related References:

1. K.L. Scrivener, V. John, E.M. Gartner, Eco-efficient cements: potential, economically viable solutions for a low-CO2, cement-based materials industry, in: United Nations Environmental Programme (UNEP), 2016.

2. B. Lothenbach, K. Scrivener, R.D. Hooton, Supplementary cementitious materials, Cement and Concrete Research. 41 (2011) 1244–1256. doi: 10.1016/j.cemconres.2010.12.001

3. M. Schneider, M. Romer, M. Tschudin, H. Bolio, Sustainable cement production—present and future, Cement and Concrete Research. 41 (2011) 642–650. doi: 10.1016/j.cemconres.2011.03.019

4. IEA, Cement Technology Roadmap: Carbon Emissions Reductions up to 2050, OECD Publishing, Paris, n.d. doi: 10.1787/9789264088061-en

5. K. Scrivener, F. Avet, H. Maraghechi, F. Zunino, J. Ston, W. Hanpongpun, A. Favier, Impacting factors and properties of limestone calcined clay cements (LC3), Green Materials. 7 (2019) 3–14. doi: 10.1680/jgrma.18.00029

6. F. Zunino, Limestone calcined clay cements (LC3): raw material processing, sulfate balance and hydration kinetics, EPFL Thesis 8173, 2020.

7. R.G. Pillai, R. Gettu, M. Santhanam, S. Rengaraju, Y. Dhandapani, S. Rathnarajan, A.S. Basavaraj, Service life and life cycle assessment of reinforced concrete systems with limestone calcined clay cement (LC3), Cement and Concrete Research. 118 (2019) 111–119. doi: 10.1016/j.cemconres.2018.11.019

8. F. Zunino, F. Martirena, K. Scrivener, Limestone calcined clay cements (LC3), ACI Materials Journal. (In press.).

9. I.N.N., NCh148.Of68 : Cemento – Terminología , clasificación y especificaciones generales, 1968.

10. X. Li, R. Snellings, M. Antoni, N.M. Alderete, M. Ben Haha, S. Bishnoi, Ö. Cizer, M. Cyr, K. De Weerdt, Y. Dhandapani, J. Duchesne, J. Haufe, D. Hooton, M. Juenger, S. Kamali-Bernard, S. Kramar, M. Marroccoli, A.M. Joseph, A. Parashar, C. Patapy, J.L. Provis, S. Sabio, M. Santhanam, L. Steger, T. Sui, A. Telesca, A. Vollpracht, F. Vargas, B. Walkley, F. Winnefeld, G. Ye, M. Zajac, S. Zhang, K.L. Scrivener, Reactivity tests for supplementary cementitious materials: RILEM TC 267-TRM phase 1, Mater Struct. 51 (2018) 151. doi: 10.1617/s11527-018-1269-x

11. F. Zunino, K. Scrivener, The influence of the filler effect on the sulfate requirement of blended cements, Cement and Concrete Research. 126 (2019) 105918. doi: 10.1016/j.cemconres.2019.105918

12. ASTM C1897, Standard Test Methods for Measuring the Reactivity of Supplementary Cementitious Materials by Isothermal Calorimetry and Bound Water Measurements, 2020. doi: 10.1520/C1897-20.2

13. F. Zunino, K. Scrivener, The reaction between metakaolin and limestone and its effect in porosity refinement

and mechanical properties, Cement and Concrete Research. 140 (2021). doi: 10.1016/j.cemconres.2020.106307

14. E. Berodier, K. Scrivener, Understanding the filler effect on the nucleation and growth of C-S-H, Journal of the American Ceramic Society. 97 (2014) 3764–3773. doi: 10.1111/jace.13177

15. M. Antoni, Investigation of cement substitution by combined addition of calcined clays and limestone, École Polytechnique Fédérale de Lausanne, 2011.

16. F. Zunino, K. Scrivener, Factors influencing the sulfate balance in pure phase C3S/C3A systems, Cement and Concrete Research. 133 (2020) 106085. doi: 10.1016/j.cemconres.2020.106085

17. F. Avet, R. Snellings, A. Alujas Diaz, M. Ben Haha, K. Scrivener, Development of a new rapid, relevant and reliable (R3) test method to evaluate the pozzolanic reactivity of calcined kaolinitic clays, Cement and Concrete Research. 85 (2016) 1–11. doi: 10.1016/j.cemconres.2016.02.015