Sulfate Resistance and Hydration Products of Steam Cured GGBFS Blended Cement Mortar

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Title: Sulfate Resistance and Hydration Products of Steam Cured GGBFS Blended Cement Mortar

Author(s): Baoliang Li, Binbin Huo, and Yamei Zhang

Publication: Symposium Paper

Volume: 330

Issue:

Appears on pages(s): 205-218

Keywords: GGBFS; mortar; steam curing; dry-wet cycle; sulfate attack; strength; hydration products

DOI: 10.14359/51711252

Date: 9/26/2018

Abstract:
To meet the requirements of building industrialization of construction, steam curing is widely used to produce concrete elements in factories in China. However, there are few reports relating to the properties of steam cured concrete under dry-wet cycle and sulfate attack. The performance of steam cured (80°C (176°F) for 7h) GGBFS blended cement mortar (20% cement is substituted by GGBFS) under sulfate attack and dry-wet cycle condition were investigated. Under dry-wet cycle, both steam cured and standard cured GGBFS mortar present worse sulfate resistance compared with those of pure cement mortar. However, early age steam curing improves the sulfate resistance of GGBFS mortar, but decreases the sulfate resistance of pure cement mortar. The formation of hemicarbonate and C-A-S-H under steam curing seems to be beneficial for protecting against the sulfate attack of cement mortar, but the coarse pore structure caused by steam cuing is harmful to the sulfate resistance of cement mortar.

Related References:

1. Ganjian, E., and Pouya, H. S., “Effect of magnesium and sulfate ions on durability of silica fume blended mixes exposed to the seawater tidal zone,” Cement and Concrete Research, V. 35, No. 7, 2005, pp. 1332-1343. doi: 10.1016/j.cemconres.2004.09.028

2. Nehdi, M., and Hayek, M., “Behavior of blended cement mortars exposed to sulfate solutions cycling in relative humidity,” Cement and Concrete Research, V. 35, No. 4, 2005, pp. 731-742. doi: 10.1016/j.cemconres.2004.05.032

3. Hu, S. G.; Qin, L. X.; Ding, Q. J.; and Xiong, X. P., “Influence of slag on sulfate resistance of concrete,” Journal of Wuhan University of Technology, V. V20, No. 1, 1998, pp. 1-3.

4. Al-Akhras, N. M., “Durability of metakaolin concrete to sulfate attack,” Cement and Concrete Research, V. 36, No. 9, 2006, pp. 1727-1734. doi: 10.1016/j.cemconres.2006.03.026

5. Jin, Y. N., and Zhou, S. X., “Types and Mechanism of Concrete Sulfate Attack,” Journal of East China Jiaotong University, V. 23, No. 5, 2006, pp. 4-8.

6. Gollop, R. S., and Taylor, H. F. W., “Microstructural and microanalytical studies of sulfate attack. IV. Reactions of a slag cement paste with sodium and magnesium sulfate solutions,” Cement and Concrete Research, V. 26, No. 7, 1996, pp. 1013-1028. doi: 10.1016/0008-8846(96)00089-0

7. O’Connell, M.; McNally, C.; and Richardson, M. G., “Biochemical attack on concrete in wastewater applications: A state of the art review,” Cement and Concrete Composites, V. 32, No. 7, 2010, pp. 479-485. doi: 10.1016/j.cemconcomp.2010.05.001

8. Osborne, G. J., “The effectiveness of a carbonated outer layer to concrete in the prevention of sulphate attack,” Protection of Concrete: Proceedings of the International Conference, University of Dundee, September 1990. CRC Press, 2003, pp. 66-81.

9. Osborne, G. J., “Durability of Portland blast-furnace slag cement concrete,” Cement and Concrete Composites, V. 21, No. 1, 1999, pp. 11-21. doi: 10.1016/S0958-9465(98)00032-8

10. Neville, A. M., Properties of Concrete, 4th edition, Addison Wesley Longman Limited, UK, 1995.

11. Gollop, R. S., and Taylor, H. F. W., “Microstructural and microanalytical studies of sulfate attack. V. Comparison of different slag blends,” Cement and Concrete Research, V. 26, No. 7, 1996, pp. 1029-1044. doi: 10.1016/0008-8846(96)00090-7

12. Cassagnabère, F.; Mouret, M.; and Escadeillas, G., “Early hydration of clinker–slag–metakaolin combination in steam curing conditions, relation with mechanical properties,” Cement and Concrete Research, V. 39, No. 12, 2009, pp. 1164-1173. doi: 10.1016/j.cemconres.2009.07.023

13. Kjellsen, K. O., “Heat curing and post-heat curing regimes of high-performance concrete: Influence on microstructure and C-S-H composition,” Cement and Concrete Research, V. 26, No. 2, 1996, pp. 295-307. doi: 10.1016/0008-8846(95)00202-2

14. Erdem, T. K.; Turanli, L.; and Erdogan, T. Y., “Setting time: An important criterion to determine the length of the delay period before steam curing of concrete,” Cement and Concrete Research, V. 33, No. 5, 2003, pp. 741-745. doi: 10.1016/S0008-8846(02)01058-X

15. Ho, D. W. S.; Chua, C. W.; and Tam, C. T., “Steam-cured concrete incorporating mineral admixtures,” Cement and Concrete Research, V. 33, No. 4, 2003, pp. 595-601. doi: 10.1016/S0008-8846(02)01028-1

16. Taylor, H. F. W.; Famy, C.; and Scrivener, K. L., “Delayed ettringite formation,” Cement and Concrete Research, V. 31, No. 5, 2001, pp. 683-693. doi: 10.1016/S0008-8846(01)00466-5

17. Wu, Z. W., and Lian, H. Z., “High Performance Concrete,” Chinese Railway Press, Beijing, 1999.

18. Liu, R. G., “Hydration mechanism and long–term performance of cement–slag complex cementitious materials,” Doctoral dissertation, Tsinghua University, 2013.

19. Zajac, M.; Rossberg, A.; Le Saout, G.; and Lothenbach, B., “Influence of limestone and anhydrite on the hydration of Portland cements,” Cement and Concrete Composites, V. 46, No. 4, 2014, pp. 99-108. doi: 10.1016/j.cemconcomp.2013.11.007

20. Kakali, G.; Tsivilis, S.; Aggeli, E.; and Bati, M., “Hydration products of C3A, C3S and Portland cement in the presence of CaCO3,” Cement and Concrete Research, V. 30, No. 7, 2000, pp. 1073-1077. doi: 10.1016/S0008-8846(00)00292-1

21. Whittaker, M.; Zajac, M.; Haha, M. B.; and Black, L., “The impact of alumina availability on sulfate resistance of slag composite cements,” Construction & Building Materials, V. 119, 2016, pp. 356-369. doi: 10.1016/j.conbuildmat.2016.05.015

22. Bahafid, S.; Ghabezloo, S.; Duc, M.; Faure, P.; and Sulem, J., “Effect of the hydration temperature on the microstructure of Class G cement: C-S-H composition and density,” Cement and Concrete Research, V. 95, 2017, pp. 270-281. doi: 10.1016/j.cemconres.2017.02.008