Title:
Development of Test Methods and Specifications for Chemically Activated Binders
Author(s):
R. Douglas Hooton, Lawrence Sutter, and Mary Christiansen
Publication:
Symposium Paper
Volume:
320
Issue:
Appears on pages(s):
38.1-38.12
Keywords:
alternative cements; building codes; chemically activated binders; durability tests; test methods.
DOI:
10.14359/51701076
Date:
8/1/2017
Abstract:
There has been a proliferation of research and development activity focused on chemically activated binder technologies and other alternative cements for use in concrete. Some activated binder technologies have been used successfully in construction or in manufacture of building products. However, a major barrier to adoption of such new materials is the lack of appropriate test methods and specifications, often precluding their use in structural applications since they are not covered by building codes. Some existing test methods may be suspect for evaluation of new cementing materials because they often do not relate well to field performance for portland cement concrete. However, engineers have experience, familiarity and a comfort level with using portland cement concrete. In addition to raising specific areas of concern with existing test methods, alternative approaches to adapting
existing test methods or development of new tests specific to evaluation of chemically activated binders and alternative cements are discussed.
Related References:
1. Hooton, R. D., 2015. Current Developments and Future Needs in Standards for Cementitious Materials,Cement and Concrete Research, 78 (Part A) 165-177.
2. ASTM C150/C150M-16, Specification for Portland Cement, ASTM Annual Book of Standards, V.04.01,ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
3. ASTM C109/C109M-16, Standard Test Method for Compressive Strength of Hydraulic Cement Mortars(Using 2-in. or [50-mm] Cube Specimens), ASTM Annual Book of Standards, V.04.01, ASTM International,100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
4. ASTM C595/C595M-15, Standard Specification for Blended Hydraulic Cements, ASTM Annual Book ofStandards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA(2016).
5. ASTM C618-15, Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use inConcrete, ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
6. ASTM C989/C989M-14, Standard Specification for Slag Cement for Use in Concrete and Mortars, ASTMAnnual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
7. ASTM C1157/C1157M-11 Standard Performance Specification for Hydraulic Cement, ASTM Annual Bookof Standards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PAUSA (2016).
8. ASTM C1240-15, Standard Specification for Silica Fume Used in Cementitious Mixtures, ASTM AnnualBook of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken,PA USA (2016).
9. ASTM C1600/C1600M-11Standard Specification for Rapid Hardening Hydraulic Cement, ASTM AnnualBook of Standards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken,PA USA (2016).
10. ASTM C1697-10, Standard Specification for Blended Supplementary Cementitious Materials, ASTMAnnual Book of Standards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
11. ASTM C151/151M-16, Standard Test Method for Autoclave Expansion of Hydraulic Cement, ASTMAnnual Book of Standards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
12. ASTM C1038/1038M-14, Standard Test Method for Expansion of Hydraulic Cement Mortar Bars Stored inWater, ASTM Annual Book of Standards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700,West Conshohocken, PA USA (2016).
13. ASTM C157/C157M-08, Standard Test Method for Length Change of Hardened Hydraulic-Cement Mortarand Concrete, ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. BoxC-700, West Conshohocken, PA USA (2016).
14. ASTM C596-09, Standard Test Method for Drying Shrinkage of Mortar Containing Hydraulic Cement,ASTM Annual Book of Standards, V.04.01, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
15. ASTM C1702-15, Standard Test Method for Measurement of Heat of Hydration of Hydraulic CementitiousMaterials Using Isothermal Conduction Calorimetry, ASTM Annual Book of Standards, V.04.01, ASTMInternational, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
16. van Deventer, J. S. J., 2015. Private Communication.
17. ASTM C39/C39M-16, Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens,ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
18. ASTM C31/C31M-15, Standard Practice for Making and Curing Concrete Test Specimens in the Field,ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
19. ASTM C192/192M-15, Standard Practice for Making and Curing Concrete Test Specimens in theLaboratory, ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. BoxC-700, West Conshohocken, PA USA (2016).
20. ASTM E119-16a, Standard Test Methods for Fire Tests of Building Construction and Materials, ASTMAnnual Book of Standards, V.04.07, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, WestConshohocken, PA USA (2016).
21. Lamond, J. F. and Pielert, J. H. (Eds), 2006. Significance of Tests and Properties of Concrete and Concrete-Making Materials, Special Technical Publication, STP169D. ASTM, West Conshohocken, PA.
22. ASTM C1581/C1581M-16, Standard Test Method for Determining Age at Cracking and Induced TensileStress Characteristics of Mortar and Concrete under Restrained Shrinkage, ASTM Annual Book of Standards,V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
23. Libby, J. R., 1977. Modern Prestressed Concrete - Design Principles and Construction Methods, New York,N.Y., Van Nostrand Reinhold.
24. MacGregor, J. G., 1997. Reinforced Concrete: Mechanics and Design, Prentice Hall, Opper Saddle River,NJ, Opper Saddle River, NJ.
25. ASTM A944-12, Standard Test Method for Comparing Bond Strength of Steel Reinforcing Bars to ConcreteUsing Beam-End Specimens, ASTM Annual Book of Standards, V.04.02, ASTM International, 100 BarrHarbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
26. ASTM C1556-11, Standard Test Method for Determining the Apparent Chloride Diffusion Coefficient ofCementitious Mixtures by Bulk Diffusion, ASTM Annual Book of Standards, V.04.02, ASTM International,100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
27. NORDTEST NT Build 492, 1999 (2011), “Chloride Migration Coefficient from Non-Steady StateMigration Experiments,” UDC 691.32/691.53/691.54, NORDTEST, Espoo, Finland.
28. ASTM C1202-12, Standard Test Method for Electrical Indication of Concrete’s Ability to Resist ChlorideIon Penetration, ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O.Box C-700, West Conshohocken, PA USA (2016).
29. Hooton, R. D., and Charmchi, G., 2015. Adoption of Resistivity Tests for Concrete Acceptance, Proc.Recent Advances in Concrete Technology and Sustainability Issues, ACI Special Publication SP-303, 269-279.
30. Provis, J. L. and van Deventer, J. S. J., 2014. Alkali Activated Materials: State-of-the-Art Report, RILEMTC 224-AAM, Springer, Netherlands, 338 pp.
31. Douglas E. Bilodeau, A. A. and Malhotra, V. M., 1992. Properties and Durability of Alkali-Activated SlagConcrete, ACI Materials Journal, 89(5) 509-516.
32. Provis, J. L. and van Deventer, J. S. J., 2015. Low Carbon Emission Geopolymer Concrete: from Researchinto Practice, Proc. 27th Biennial National Concrete Conference, Institute of Australia, Melbourne, Australia.
33. Rashad, A. M., Bai, Y., Basheer, P. A. M., Milestone, N. B., and Collier, N. C., 2013. Hydration andproperties of sodium sulfate activated slag, Cement and Concrete Composites, 37, 20-29.
34. Ismail, I., Bernal, S. A., Provis, J. L., Hamdan, S., and van Deventer, J. S. J., Microstructural Changes inAlkali Activated Fly Ash/Slag Geopolymers with sulfate Exposure, Materials and Structures, 46(3) 361-373.
35. Quillin, K., 2001. Performance of belite–sulfoaluminate cements, Cement and Concrete Research, 31(9)1341-1349.
36. ASTM C1260-14, Standard Test Method for Potential Alkali Reactivity of Aggregates (Mortar-BarMethod), ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr., P.O. Box C-700, West Conshohocken, PA USA (2016).
37. ASTM C1293-08(2015), Standard Test Method for Determination of Length Change of Concrete Due toAlkali-Silica Reaction, ASTM Annual Book of Standards, V.04.02, ASTM International, 100 Barr Harbor Dr.,P.O. Box C-700, West Conshohocken, PA USA (2016).
38. Gifford P. M., and Gillott, J. E., 1996. Alkali-silica reaction (ASR) and alkali-carbonate reaction (ACR) inactivated blast furnace slag cement (ABFSC) concrete, Cement and Concrete Research, 6(1) 21-26.
39. Bakharev, T, Sanjayan, J. G. and Cheng, Y. B., 2001. Resistance of alkali-activated slag concrete to alkali–aggregate reaction, Cement and Concrete Research, 31(2) 331-334.
40. Lloyd, R. R., Provis, J. L., and van Deventer, J. S. J., 2010. Pore solution composition and alkali diffusion ininorganic polymer cement, Cement and Concrete Research, 40(9) 1386-1392.
41. Hewlett P. C. (Ed.), 1998. Lea's Chemistry of Cement and Concrete: 4th Ed, Arnold, ISBN 0-340-56589-6,Chapter 13.
42. Miller, J. S. and Bellinger, W. J., 2014. Distress Identification Manual For The Long-Term Pavement PerformanceProgram (Fifth Revised Edition), Office Of Infrastructure Research And Development, Federal HighwayAdministration, 6300 Georgetown Pike, Mclean, VA 22101-2296, 142 pp.
43. ACI/ICRI, 2016. Guide to the Code for Assessment, Repair, and Rehabilitation of Existing ConcreteStructures (562MAN-16), American Concrete Institute/International Concrete Repair Institute Joint Document,1000 Westgate Drive, Suite 252; Saint Paul, MN 55114 USA.
44. ACI 318-14, 2014. Building Code Requirements for Structural Concrete and Commentary, AmericanConcrete Institute, Farmington Hills, MI, USA.
45. ATI-10, 2016. Report on Alternative Cements (L. Sutter, Ed.), American Concrete Institute, FarmingtonHills, MI (under review by TAC), 127 pp.