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Title: Changes in Concrete Pore Size Distribution Due to Electrochemical Chloride Migration Trials

Author(s): Marta Castellote, Carmen Andrade, and Ma Cruz Alonso

Publication: Materials Journal

Volume: 96

Issue: 3

Appears on pages(s): 314-319

Keywords: concretes; microstructure; porosity

DOI: 10.14359/628

Date: 5/1/1999

Abstract:
Advanced repair techniques, such as electrochemical chloride removal and re-alkalization involving the use of electrical current applied, are starting to be used for the rehabilitation of concrete structures. The generalized movement of ions dissolved in the aqueous phase of pores leads the authors to conclude that the microstructure of concrete can be altered. In the present paper, results are presented on the changes in pore size distribution after penetration of chlorides driven by an electrical field (migration) in comparison with natural diffusion penetration. Results indicate that the application of an electrochemical treatment to a structure induces an increase in total porosity, due to the solution of precipitated phases, initially located in the smallest capillary pores that after some time evolve to be found in the range between 5 and 0.05 mm.


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