Title:
Synthesis of Innovative Superplasticizers and Their Impact on the Properties of Concrete (Prepublished)
Author(s):
Mohamed Saeed Mohamed, Mohamed El-Sayed Sultan, Ahmed Galal Ibrahim, Farag Ahmed Abd El-Hai
Publication:
Materials Journal
Volume:
Issue:
Appears on pages(s):
Keywords:
iso amyl alcohol polyethylene glycol, grout, methoxy polyethylene glycol methacrylate, polycarboxylate ether, superplasticizers
DOI:
10.14359/51749323
Date:
11/13/2025
Abstract:
In this work, novel polycarboxylate admixtures were synthesized by two different free radical polymerization systems of methacrylic acid (MAA) and methoxy polyethylene glycol methacrylate (MPEG-MA) for PC-1, and acrylic acid (AA) and iso amyl alcohol polyethylene glycol (IAA-PEG) for PC-2. Thioglycolic acid as a chain transfer agent and ammonium persulphate as an initiator were used. The synthesized carboxylic polymers were characterized using FTIR, H-NMR, gel permeation chromatography (GPC), and thermogravimetric analysis (TGA). The influence of the chemical structure of polycarboxylates on the rheology of the concrete, as well as the prognosis of the superplasticizer’s development, is also presented through measuring water consistency, setting times, flow table, slump test, Zeta potential, and compressive strength. The cementitious products were investigated with X-ray diffraction (XRD) and scanning electron microscope (SEM). The developed superplasticizers have shown good dispersion effects and slump performance in workability and fluidity retention tests, adsorption performance, and scanning electron microscopy performance. Intriguingly, the PC-1 and PC-2 mixes achieved flow table values of 230 and 200 mm, respectively. The compressive strength values at various curing ages up to 28 days exhibited double and triple values compared with the control sample. Additionally, compared to the control ordinary Portland cement paste, a reduction of water-to-cement ratio of about 0.25 and the development of excessive hydration products give PC-1 and PC-2 extensive pastes a more dense and compact structure in XRD and SEM investigation.