Investigation on Microstructure of Cement Pastes Made with a By-Product from Primary Aluminum Production

International Concrete Abstracts Portal

The International Concrete Abstracts Portal is an ACI led collaboration with leading technical organizations from within the international concrete industry and offers the most comprehensive collection of published concrete abstracts.

  


Title: Investigation on Microstructure of Cement Pastes Made with a By-Product from Primary Aluminum Production

Author(s): Hang Tran, Victor Brial, Thomas Sanchez, Luca Sorelli, Claudiane Ouellet-Plamondon, David Conciatori, Houshang D. Alamdari, Mario Fafard, Laurent Birry And Martin Beaulieu

Publication: Symposium Paper

Volume: 349

Issue:

Appears on pages(s): 686-695

Keywords: microstructure, micro-indentation, spent pot lining, SEM, XRD

DOI: 10.14359/51732781

Date: 4/22/2021

Abstract:
Spent pot lining (SPL) is an industrial waste generated from aluminum electrolysis cells. LCLL-ash is the inert by-product coming from the treatment of the SPL refractory fraction at the SPL treatment plant (Jonquière, Canada). LCLL-ash has been ground to the fineness of the cement to substitute a part of cement in cement pastes. However, LCLL-ash contains higher contents of silica and alumina compared to Portland cement, which can affect the composition, the morphology and the mechanical properties of the binder hydrates (e.g. the Calcium-[Aluminum]- Silicate Hydrates, C-[A]-S-H) with an important effect on the durability. This paper focuses on the investigation of the microstructure and the mechanical properties of LCLL blended cement pastes by applying multiple techniques including scanning electron microscopy, X-ray diffraction, and microindentation at the level of the cement paste. The water-to-binder ratio (w/b) is fixed at 0.35. The effect of the different proportions of LCLL-ash on the microstructural and mechanical properties of blended cement pastes is presented and discussed with relation to the normal Portland cement paste.

Related References:

1. L. Scrivener K., M. John V., M. Gartner.E, Eco-efficient cements: Potential economically viable solutions for a low-CO2 cement-based materials industry, (2016).

2. R.M. Andrew, Global CO2 emissions from cement production, Open Access. (2017) 52.

3. I. Rustad, K.H. Karstensen, K.E. Ødegrd, Disposal options for spent potlining, in: G.R. Woolley, J.J.J.M. Goumans, P.J. Wainwright (Eds.), Waste Management Series, Elsevier, 2000: pp. 617–632. http://www.sciencedirect.com/science/article/pii/S0713274300800720 (accessed October 9, 2018).

4. F.M. Kimmerle, V. Kasireddy, J.G. Tellier, SPL treatment by the LCL&L process: Pilot study of two-stage leaching, Light Metals. (2001).

5. G. Fares, Nouveau systèmecimentaire: casde la Frittede verre(New CementitiousSystem: the case of Glass Frit)., (2008).

6. M. Zajac, A. Rossberg, G. Le Saout, B. Lothenbach, Influence of limestone and anhydrite on the hydration of Portland cements, Cement and Concrete Composites. 46 (2014) 99–108. doi: 10/ggrbdh.

7. C01 Committee, Practice for High-Shear Mixing of Hydraulic Cement Pastes, ASTM International, n.d. doi: 10.1520/C1738_C1738M-14

8. X. Wang, A.B. Eberhardt, K.L. Scrivener, E. Gallucci, Assessing Early Age Properties Of Cementitious Systems By Water-Isopropanol Replacement, in: 2014.

9. The suitability of solvent exchange techniques for studying the pore structure of hardened cement paste | M.D.A. Thomas, ResearchGate. (n.d.).

10. J. Frech-Baronet, L. Sorelli, J.-P. Charron, New evidences on the effect of the internal relative humidity on the creep and relaxation behaviour of a cement paste by micro-indentation techniques, Cement and Concrete Research. 91 (2017) 39–51. doi: 10/f9hpsq

11. Q. Zhang, R. Le Roy, M. Vandamme, B. Zuber, Long-term creep properties of cementitious materials: Comparing microindentation testing with macroscopic uniaxial compressive testing, Cement and Concrete Research. 58 (2014) 89–98. doi: 10.1016/j.cemconres.2014.01.004

12. F.-J. Ulm, M. Vandamme, C. Bobko, J.A. Ortega, K. Tai, C. Ortiz, Statistical Indentation Techniques for Hydrated Nanocomposites: Concrete, Bone, and Shale, Journal of the American Ceramic Society. 90 (2007) 2677–2692. doi: 10.1111/j.1551-2916.2007.02012.x

13. F.-J. Ulm, M. Vandamme, H.M. Jennings, J. Vanzo, M. Bentivegna, K.J. Krakowiak, G. Constantinides, C.P. Bobko, K.J. Van Vliet, Does microstructure matter for statistical nanoindentation techniques?, Cement and Concrete Composites. 32 (2010) 92–99. doi: 10.1016/j.cemconcomp.2009.08.007

14. M. Miller, C. Bobko, M. Vandamme, F.-J. Ulm, Surface roughness criteria for cement paste nanoindentation, Cement and Concrete Research. 38 (2008) 467–476. doi: 10/bpc9km

15. W.C. Oliver, G.M. Pharr, An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments, Journal of Materials Research. 7 (1992) 1564–1583. doi: 10/bdv47f

16. Zhang, L. Glasser, F. P., Critical examination of drying damage to cement pastes, (2000). doi: 10/bccwfn

17. T. Matschei, B. Lothenbach, F.P. Glasser, The AFm phase in Portland cement, Cement and Concrete Research. 37 (2007) 118–130. doi: 10.1016/j.cemconres.2006.10.010

18. E. L’Hôpital, B. Lothenbach, G. Le Saout, D. Kulik, K. Scrivener, Incorporation of aluminium in calciumsilicate-hydrates, Cement and Concrete Research. 75 (2015) 91–103. doi: 10/f7jgkv

19. C.P. Bobko, B. Gathier, J.A. Ortega, F.-J. Ulm, L. Borges, Y.N. Abousleiman, The nanogranular origin of friction and cohesion in shale—a strength homogenization approach to interpretation of nanoindentation results, International Journal for Numerical and Analytical Methods in Geomechanics. 35 (2011) 1854–1876.

20. A.C. Fischer-Cripps, Nanoindentation Springer, New York. (2004).

21. A.M. Akasha, J.M. Abdullah, Sulfate Resistance of Cement Mortar Containing Metakaolin, in: F. Martirena, A. Favier, K. Scrivener (Eds.), Calcined Clays for Sustainable Concrete, Springer Netherlands, Dordrecht, 2018: pp. 8–14. doi: 10.1007/978-94-024-1207-9_2

22. C. Hu, Microstructure and mechanical properties of fly ash blended cement pastes, Construction and Building Materials. 73 (2014) 618–625. doi: 10.1016/j.conbuildmat.2014.10.009.

23. S. Ibrahim, A. A. Hagrass, T. R. Boulos, S. I. Youssef, F. I. El-Hossiny, M. R. Moharam, Metakaolin as an Active Pozzolan for Cement That Improves Its Properties and Reduces Its Pollution Hazard, Journal of Minerals and Materials Characterization and Engineering. 06 (2018) 86–104. doi: 10.4236/jmmce.2018.61008

24. T.H.Y. Nguyen, K. Tsuchiya, D. Atarashi, Microstructure and composition of fly ash and ground granulated blast furnace slag cement pastes in 42-month cured samples, Construction and Building Materials. 191 (2018) 114–124. doi: 10.1016/j.conbuildmat.2018.09.206