An Innovative Approach to Fly Ash Characterization and Evaluation to Prevent Alkali-Silica Reaction

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Title: An Innovative Approach to Fly Ash Characterization and Evaluation to Prevent Alkali-Silica Reaction

Author(s): Anol K. Mukhopadhyay, Kai-Wei Liu, and Mostafa Jalal

Publication: Materials Journal

Volume: 116

Issue: 4

Appears on pages(s): 173-181

Keywords: accelerated concrete cylinder test (ACCT); advanced characterization; alkali silica reaction (ASR); emerging test methods; fly ash; pozzolans; quantitative X-ray diffraction (QXRD)

DOI: 10.14359/51716751

Date: 7/1/2019

Abstract:
The main objective of this study was to conduct a full-scale characterization of different types of fly ashes using conventional as well as advanced techniques and evaluating their effectiveness to prevent alkali-silica reaction (ASR) using an emerging accelerated concrete cylinder test (ACCT). The full-scale characterization of fly ashes involves evaluation of type and content of crystalline phases and amorphous content by quantitative X-ray diffraction (QXRD), soluble available alkalis (ASTM C311), and pore solution chemistry along with determination of parameters by the conventional ASTM C618. A favorable comparison between characteristic chemical and mineralogical parameters of the fly ashes and ACCT-based ASR performance prediction was observed. This combined innovative approach was found to be effective to test the effectiveness (optimization) of different types of fly ashes to prevent ASR in a rapid (within 75 days) and reliable manner and formulate case-specific, performance-based, ASR-resistant concrete mixtures using locally available fly ashes.

Related References:

1. Latifee, E. R., “State-of-the-Art Report on Alkali Silica Reactivity Mitigation Effectiveness Using Different Types of Fly Ashes,” Journal of Materials, V. 2016, 2016, 7 pp. doi: 10.1155/2016/7871206

2. Liu, K. W.; Mukhopadhyay, A. K.; Shi, X.; and Hsu, J. H., “Chemical Approaches to Prevent Alkali-Silica Reaction in Concrete—A Review,” Engineering Solid Mechanics, V. 6, No. 3, 2018, pp. 201-208. doi: 10.5267/j.esm.2018.6.003

3. Shehata, M. H., and Thomas, M. D., “Use of Ternary Blends Containing Silica Fume and Fly Ash to Suppress Expansion Due to Alkali-Silica Reaction in Concrete,” Cement and Concrete Research, V. 32, No. 3, 2002, pp. 341-349. doi: 10.1016/S0008-8846(01)00680-9

4. Ramlochan, T.; Thomas, M.; and Gruber, K. A., “The Effect of Metakaolin on Alkali-Silica Reaction in Concrete,” Cement and Concrete Research, V. 30, No. 3, 2000, pp. 339-344. doi: 10.1016/S0008-8846(99)00261-6

5. Duchesne, J., and Berube, M., “Relationships between Portlandite Depletion, Available Alkalis and Expansion of Concrete Made with Mineral Admixtures,” Proceedings of the 9th International Conference on Alkali-Aggregate Reaction in Concrete, V. 1. 1992, pp. 287-297.

6. Boddy, A.; Hooton, R.; and Thomas, M., “The Effect of the Silica Content of Silica Fume on its Ability to Control Alkali-Silica Reaction,” Cement and Concrete Research, V. 33, No. 8, 2003, pp. 1263-1268. doi: 10.1016/S0008-8846(03)00058-9

7. Bleszynski, R. F., “The Performance and Durability of Concrete with Ternary Blends of Silica Fume and Blast-Furnace Slag,” PhD dissertation, University of Toronto, Toronto, ON, Canada, 2003.

8. Shahzad Baig, K., and Yousaf, M., “Coal Fired Power Plants: Emission Problems and Controlling Techniques,” Journal of Earth Science & Climatic Change, V. 8, No. 404, 2017, pp. 1-9.

9. Sloss, L. L., “Blending of Coals to Meet Power Station Requirements,” IEA Clean Coal Centre, 2014, pp.1-68.

10. Gava, G., and Prudencio, L., Jr., “Pozzolanic Activity Tests as a Measure of Pozzolans’ Performance. Part 1,” Magazine of Concrete Research, V. 59, No. 10, 2007, pp. 729-734. doi: 10.1680/macr.2007.59.10.729

11. Gava, G., and Prudencio, L., Jr., “Pozzolanic Activity Tests as a Measure of Pozzolans’ Performance. Part 2,” Magazine of Concrete Research, V. 59, No. 10, 2007, pp. 735-741. doi: 10.1680/macr.2007.59.10.735

12. Pourkhorshidi, A.; Najimi, M.; Parhizkar, T.; Jafarpour, F.; and Hillemeier, B., “Applicability of the Standard Specifications of ASTM C618 for Evaluation of Natural Pozzolans,” Cement and Concrete Composites, V. 32, No. 10, 2010, pp. 794-800. doi: 10.1016/j.cemconcomp.2010.08.007

13. Pourkhorshidi, A.; Najimi, M.; Parhizkar, T.; Hillemeier, B.; and Herr, R., “A Comparative Study of the Evaluation Methods for Pozzolans,” Advances in Cement Research, V. 22, No. 3, 2010, pp. 157-164. doi: 10.1680/adcr.2010.22.3.157

14. Seraj, S.; Cano, R.; Liu, S.; Whitney, D.; Fowler, D.; Ferron, R.; Zhu, J.; and Juenger, M., “Evaluating the Performance of Alternative Supplementary Cementing Material in Concrete,” Report No. FHWA/TX-14/0-6717-1, Texas Department of Transportation, Austin, TX, 2014, 143 pp.

15. Thomas, M., and Folliard, K., “Concrete Aggregates and the Durability of Concrete,” Durability of Concrete and Cement Composites, Woodhead Publishing Limited, Cambridge, UK, 2007, pp. 247-281.

16. Tremblay, C.; Bérubé, M. A.; Fournier, B.; Thomas, M. D.; and Folliard, K. J., “Effectiveness of Lithium-Based Products in Concrete Made with Canadian Natural Aggregates Susceptible to Alkali-Silica Reactivity,” ACI Materials Journal, V. 104, No. 2, Mar.-Apr. 2007, pp. 195-205.

17. Shehata, M. H., and Thomas, M. D., “The Effect of Fly Ash Composition on the Expansion of Concrete Due to Alkali-Silica Reaction,” Cement and Concrete Research, V. 30, No. 7, 2000, pp. 1063-1072. doi: 10.1016/S0008-8846(00)00283-0

18. Sutter, L. L.; Hooton, R. D.; and Schlorholtz, S., “Methods for Evaluating Fly Ash for Use in Highway Concrete,” NCHRP Report 749, Transportation Research Board, Washington, DC, 2013.

19. Winburn, R. S.; Lerach, S. L.; Jarabek, B. R.; Wisdom, M. A.; Grier, D. G.; and McCarthy, G. J., “Quantitative XRD Analysis of Coal Combustion By-Products by the Rietveld Method. Testing with Standard Mixtures,” Advances in X-ray Analysis, V. 42, 2000, pp. 387-396.

20. Mukhopadhyay, A. K., and Liu, K. W., “ASR Testing: A New Approach to Aggregate Classification and Mix Design Verification: Technical Report,” Texas Department of Transportation, Research and Technology Implementation Office, Austin, TX, 2014.

21. Liu, K. W., and Mukhopadhyay, A. K., “Accelerated Concrete-Cylinder Test for Alkali–Silica Reaction,” Journal of Testing and Evaluation, V. 44, No. 3, 2015, pp. 1229-1238.

22. Mukhopadhyay, A. K., and Liu, K. W., “Developing a Rapid Cylinder Test for Determination of Length Change of Concrete due to Alkali-Silica Reaction,” Transportation Research Board 95th Annual Meeting, No. 16-6171, 2016.

23. Mukhopadhyay, A. K.; Liu, K. W.; and Jalal, M., “Further Validation of ASR Testing and Approach for Formulating ASR-Resistant Mix,” Texas Department of Transportation, Research and Technology Implementation Office, Austin, TX, 2018.

24. Barneyback, R. Jr., and Diamond, S., “Expression and Analysis of Pore Fluids from Hardened Cement Pastes and Mortars,” Cement and Concrete Research, V. 11, No. 2, 1981, pp. 279-285. doi: 10.1016/0008-8846(81)90069-7

25. Dhole, R.; Thomas, M. D.; Folliard, K. J.; and Drimalas, T., “Sulfate Resistance of Mortar Mixtures of High-Calcium Fly Ashes and Other Pozzolans,” ACI Materials Journal, V. 108, No. 6, Nov.-Dec. 2011, pp. 645-654.

26. Mukhopadhyay, A. K., and Liu, K. W., “Innovative Approach for Formulating ASR-Resistant Mixtures,” Concrete International, V. 40, No. 12, Dec. 2018, pp. 39-45.


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