Chloride Diffusivity through Partially Saturated, Binary-Blended Concrete

International Concrete Abstracts Portal

The International Concrete Abstracts Portal is an ACI led collaboration with leading technical organizations from within the international concrete industry and offers the most comprehensive collection of published concrete abstracts.

  


Title: Chloride Diffusivity through Partially Saturated, Binary-Blended Concrete

Author(s): Yu-You Wu, Francisco J. Presuel-Moreno, and Ronald Simmons

Publication: Materials Journal

Volume: 115

Issue: 5

Appears on pages(s): 695-705

Keywords: chloride; diffusivity; fly ash; mortar layer; partially saturated concrete; water saturation degree

DOI: 10.14359/51702346

Date: 9/1/2018

Abstract:
The surface of concrete at the tidal, splash, and atmospheric regions of partially immersed marine structures experiences different degrees of water saturation. Hence, the concrete pore structure is partially filled with water at some of these regions. The present work experimentally investigates chloride transport into partially saturated concrete with 20% fly ash replacement, and the effect of the mortar layer/concrete surface condition on chloride diffusivity at four degrees of water saturation relevant to the Florida marine environments. The results indicate that the mortar layer of concrete provides protection against chloride penetration, leading to lower chloride diffusivity values. Moreover, chloride diffusivity as a function of the degree of water saturation for concrete with and without mortar layers is found to be different. The diffusivity of the former hardly changes when the degree of water saturation increases from 70 to 80%.

Related References:

1. Gjørv, O. E., Durability Design of Concrete Structures in Severe Environments, second edition, CRC Press, Boca Raton, FL, Feb. 7, 2014, 270 pp.

2. Neilson, E. P., and Geiker, M. R., “Chloride Diffusion in Partially Saturated Cementitious Materials,” Cement and Concrete Research, V. 33, No. 1, 2003, pp. 133-138. doi: 10.1016/S0008-8846(02)00939-0

3. Parrot, L. J., “Moisture Conditioning and Transport Properties of Concrete Test Specimens,” Materials and Structures, V. 27, Oct. 1994, pp. 460-468. doi: 10.1007/BF02473450

4. Martys, N. S., “Diffusion in Partially-Saturated Porous Materials,” Materials and Structures, V. 32, Oct. 1999, pp. 555-562. doi: 10.1007/BF02480489

5. Chatterji, S., “On the Non-Applicability of Unmodified Fick’s Law to Ion Transport through Cement Based Materials,” Proceedings of the 1st International Workshop on Chloride Penetration into Concrete, RILEM Publication, Saint-Rémy-lès-Chevreuse, France, 1997, pp. 64-73.

6. Climent, M. A.; de Vera, G.; Lopez, J. F.; Viqueira, E.; and Andrade, C., “A Test Method for Measuring Chloride Diffusion Coefficients through Nonsaturated Concrete. Part I: The Instantaneous Plane Source Diffusion Case,” Cement and Concrete Research, V. 32, No. 7, 2002, pp. 1113-1123. doi: 10.1016/S0008-8846(02)00750-0

7. Vera, G., Climent, M. A.; Viqueira, E.; Anton, C.; and Andrade, C., “A Test Method for Measuring Chloride Diffusion Coefficients through Nonsaturated Concrete. Part II: The Instantaneous Plane Source Diffusion Case with Chloride Binding Consideration,” Cement and Concrete Research, V. 37, No. 5, 2007, pp. 714-724. doi: 10.1016/j.cemconres.2007.01.008

8. Guimaraes, A. T. C., and Helene, P. R. L., “The Moisture Effect on the Diffusion of Chloride Ions in Hydrated Cement Paste,” Proceedings of the International Symposium on Marine Corrosion in Tropical Environments, C.S.W. Dean, G. H. Degadillo, and J. B. Bushman, eds., ASTM STP 1399, Philadelphia, PA, 2000, pp. 135-149.

9. Guimaraes, A. T. C., and Helene, P. R. L., “Models of Variation of Chloride Ion Diffusion as a Function of Changes in the Saturation Degree of Concrete Mixes Prepared with Pozzolanic Cement,” R. M. Ferreira, J. Gulikers, and C. Andrade, eds., Proceedings of the International RILEM Workshop on Integral Service Life Modelling of Concrete Structures, RILEM Publications, Cachan, France, 2007, pp. 63-70.

10. Guimaraes, A. T. C.; Climent, M. A.; de Vera, G.; Vicente, F. J.; Rodrigues, F. T.; and Andrade, C., “Determination of Chloride Diffusivity through Partially Saturated Portland Concrete by a Simplified Procedure,” Construction and Building Materials, V. 25, No. 2, 2011, pp. 785-790. doi: 10.1016/j.conbuildmat.2010.07.005

11. Olsson, N.; Baroghel-Bouny, V.; Nilsson, L. O.; and Thiery, M., “Non-Saturated Ion Diffusion in Concrete—A New Approach to Evaluate Conductivity Measurements,” Cement and Concrete Composites, V. 40, July 2013, pp. 40-47. doi: 10.1016/j.cemconcomp.2013.04.001

12. Mercado-Mendoza, H.; Lorente, S.; and Bourbon, X., “Ionic Aqueous Diffusion through Unsaturated Cementitious Materials—A Comparative Study,” Construction and Building Materials, V. 51, No. 31, 2014, pp. 1-8. doi: 10.1016/j.conbuildmat.2013.10.026

13. Zhang, M.; Ye, G.; and van Breugel, K., “Modelling of Ionic Diffusivity in Non-Saturated Cement-Based Materials Using Lattice Boltzmann Method,” Cement and Concrete Research, V. 42, No. 11, 2012, pp. 1524-1533. doi: 10.1016/j.cemconres.2012.08.005

14. Mangat, P. S.; Khatib, J. M.; and Molloy, B. T., “Microstructure, Chloride Diffusion and Reinforcement Corrosion in Blended Cement Paste and Concrete,” Cement and Concrete Composites, V. 16, No. 2, 1994, pp. 73-81. doi: 10.1016/0958-9465(94)90002-7

15. Gjørv, O. E., “Effect of Condensed Silica Fume on Steel Corrosion in Concrete,” ACI Materials Journal, V. 92, No. 6, Nov.-Dec. 1995, pp. 591-598.

16. Saraswathy, V., and Song, H. W., “Corrosion Performance of Fly Ash Blended Cement Concrete: A State-of-the-Art Review,” Corrosion Review, V. 24, Apr. 2006, pp. 87-122.

17. Yu, Z., and Ye, G., “The Pore Structure of Cement Paste Blended with Fly Ash,” Construction and Building Materials, V. 45, Aug. 2013, pp. 30-35. doi: 10.1016/j.conbuildmat.2013.04.012

18. Leng, F. G.; Feng, N. Q.; and Lu, X. Y., “An Experimental Study on the Properties of Resistance to Diffusion of Chloride Ions of Fly Ash and Blast Furnace Slag Concrete,” Cement and Concrete Research, V. 30, No. 6, 2000, pp. 989-992. doi: 10.1016/S0008-8846(00)00250-7

19. Zhang, Y., and Zhang, M., “Transport Properties in Unsaturated Cement-Based Materials—A Review,” Construction and Building Materials, V. 72, Dec. 2014, pp. 367-379. doi: 10.1016/j.conbuildmat.2014.09.037

20. Saetta, A. V.; Scotta, R. V.; and Vitaliani, R. V., “Analysis of Chloride Diffusion Into Partially Saturated Concrete,” ACI Materials Journal, V. 90, No. 5, Sept.-Oct. 1993, pp. 441-451.

21. Swaddiwudhipong, S.; Wong, S. F.; Wee, T. H.; and Lee, S. L., “Chloride Ingress In Partially And Fully Saturated Concretes,” Concrete Science and Engineering, V. 2, No. 5, 2000, pp. 17-31.

22. Oh, B. H., and Jang, S. Y., “Effects of Material and Environmental Parameters on Chloride Penetration Profiles in Concrete Structures,” Cement and Concrete Research, V. 37, No. 1, 2007, pp. 47-53. doi: 10.1016/j.cemconres.2006.09.005

23. Samson, E.; Marchand, J.; Snyder, K. A.; and Beaudoin, J. J., “Modelling Ion and Fluid Transport in Unsaturated Cement Systems in Isothermal Conditions,” Cement and Concrete Research, V. 35, No. 1, 2005, pp. 141-153. doi: 10.1016/j.cemconres.2004.07.016

24. Nguyen, T. Q.; Petkovic´, J.; Dangla, P.; and Baroghel-Bouny, V., “Modelling of Coupled Ion and Moisture Transport in Porous Building Materials,” Construction and Building Materials, V. 22, No. 11, 2008, pp. 2185-2195. doi: 10.1016/j.conbuildmat.2007.08.013

25. Baroghel-Bouny, V.; Thiéry, M.; and Wang, X., “Modelling of Isothermal Coupled Moisture-Ion Transport in Cementitious Materials,” Cement and Concrete Research, V. 41, No. 8, 2011, pp. 828-841. doi: 10.1016/j.cemconres.2011.04.001

26. Vedalakshmi, R.; Devi, R. R.; Emmanuel, B.; and Palaniswamy, N., “Determination of Diffusion Coefficient of Chloride in Concrete: An Electrochemical Impedance Spectroscopic Approach,” Materials and Structures, V. 41, No. 7, 2008, pp. 1315-1326. doi: 10.1617/s11527-007-9330-1

27. Dridi, W., and Lacour, J.-L., “Experimental Investigation of Solute Transport in Unsaturated Cement Pastes,” Cement and Concrete Research, V. 63, Sept. 2014, pp. 46-53. doi: 10.1016/j.cemconres.2014.05.002

28. Andrade, C.; Diez, J. M.; and Alonso, C., “Mathematical Modeling of a Concrete Surface ‘Skin Effect’ on Diffusion in Chloride Contaminated Media,” Advanced Cement Based Materials, V. 6, No. 2, 1997, pp. 39-44. doi: 10.1016/S1065-7355(97)00002-3

29. Kreijer, P. C., “The Skin of Concrete: Composition and Properties,” Matériaux et Constructions, V. 17, No. 4, 1984, pp. 275-283. doi: 10.1007/BF02479083

30. Presuel-Moreno, F. J.; Liu, Y.; Wu, Y.-Y.; and Arias, W., “Analysis and Estimation of Service Life Corrosion Prevention Materials Using Diffusion, Resistivity and Accelerated Curing for New Bridge Structures – Volume 1: Corrosion Prevention Materials,” Chapter 3, BDK79-977-02, Final Report Submitted to Florida Department of Transportation, Gainsville, FL, 2013.

31. Malheiro, R.; Meira, G.; Lima, M.; and Perazzo, N., “Influence of Mortar Rendering on Chloride Penetration into Concrete Structures,” Cement and Concrete Composites, V. 33, No. 2, 2011, pp. 233-239. doi: 10.1016/j.cemconcomp.2010.11.003

32. Echevarria, V., “Chloride Diffusivity and Its Correlation with Chloride Deposition Rate on Concrete Exposed to Marine Environments,” master’s thesis, Florida Atlantic University, Boca Raton, FL, Dec. 2012, 118 pp.

33. ASTM C642-06, “Standard Test Method for Density, Absorption, and Voids in Hardened Concrete, ASTM International, West Conshohocken, PA, 2006, 3 pp.

34. FM5-516, “Florida Method of Test For Determining Low-Level of Chloride in Concrete and Raw Materials,” Florida Department of Transportation, Gainsville, FL, May 13, 2009, 9 pp.

35. Crank, J., The Mathematics of Diffusion, second edition, Clarendon Press, Oxford, UK, 1975, 414 pp.

36. Thomas, M. D. A., and Bamforth, P. B., “Modelling Chloride Diffusion in Concrete: Effect of Fly Ash and Slag,” Cement and Concrete Research, V. 29, No. 4, 1999, pp. 487-495. doi: 10.1016/S0008-8846(98)00192-6

37. Cascudo, O.; Carasek, H.; Yssorche-Cubaynes, M.-P.; and Lopes, A. N.; and Oliver, J.-P., “Evaluation of Cover Concrete by Analysis of Chloride Diffusion Coefficients,” Quality of Concrete Structures and Recent Advances in Concrete Materials and Testing 2005: An International Conference Honoring V. Mohan Malhotra, SP-229, P. Helene, E. P. Figueiredo, T. C. Holland, and R. Bittencourt, eds., American Concrete Institute, Farmington Hills, MI, Sept. 2005, pp. 135-150.

38. Ramezanianpour, A. A., and Malhotra, V. M., “Effect of Curing on the Compressive Strength, Resistance to Chloride-Ion Penetration and Porosity of Concretes Incorporating Slag, Fly Ash or Silica Fume,” Cement and Concrete Composites, V. 17, No. 2, 1995, pp. 125-133. doi: 10.1016/0958-9465(95)00005-W


ALSO AVAILABLE IN:

Electronic Materials Journal



  

Edit Module Settings to define Page Content Reviewer