Corrosion Resistance of Concrete Incorporating Supplementary Cementing Materials in a Marine Environment

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Title: Corrosion Resistance of Concrete Incorporating Supplementary Cementing Materials in a Marine Environment

Author(s): Andrew Fahim, Edward G. Moffatt and Michael D.A. Thomas

Publication: Symposium Paper

Volume: 320

Issue:

Appears on pages(s): 18.1-18.14

Keywords: chloride ingress, corrosion, corrosion monitoring, marine environment, servicelife modeling, supplementary cementing materials, durability

DOI: 10.14359/51701056

Date: 8/1/2017

Abstract:
This paper presents results obtained from steel-reinforced concrete specimens retrieved after 25 to 27 years of exposure in a marine environment. The specimens included mixtures with various SCM blends (25% fly ash, 10% silica fume and 50% slag), as well as a mixture without any SCM, all at a W/CM of 0.50. Testing included chloride-ion depth determination, rapid chloride permeability test, bulk electrical resistivity test and electrochemical corrosion-monitoring. The chloride profiles revealed that SCM incorporation leads to a significant decrease in chloride-ion penetration, which was supported by rapid chloride permeability and bulk electrical resistivity tests. Electrochemical corrosionmonitoring showed passivity for all reinforcements at a cover depth of 70 mm or more for specimens incorporating SCMs, while for specimens not containing SCMs, all reinforcements, up to a cover depth of 140 mm, showed active corrosion. Finally, it was found that the reinforcement corrosion rate in SCM concrete was significantly lower than that for portland cement concrete.

Related References:

1. Thomas, M.D.A., Scott, A., Bremner, T., Bilodeau, A and Day, D., “Performance of Slag Concrete in Marine Environment”. ACI Materials Journal, 2008, pp. 628-634.

2. Thomas, M.D.A., and Bamforth, P.B., “Modelling Chloride Diffusion in Concrete: Effect of Fly Ash and Slag,” Cement and Concrete Research, 1999, Vol. 29, pp. 487-495.

3. Thomas, M.D.A and Scott, A.N., "Sustainable Concrete in a Marine Environment,” Second International Conference on Sustainable Construction Materials and Technologies, Anacona, Italy, 2010.

4. Dhir, R. K., Jones, M. R., McCarthy, M. J., “PFA concrete: Chloride-Induced Reinforcement Corrosion,” Magazine of Concrete Research, 1994, Vol. 46, No. 169, pp. 269-277.

5. Thomas, M. D. A., Hooton, R. D., Scott, A., & Zibara, H., “The Effect of Supplementary Cementitious Materials on Chloride Binding in Hardened Cement Paste,” Cement and Concrete Research, 2012, Vol. 42, No. 1, pp. 1-7.

6. Angst, U., Elsener, B., Larsen, C.K., Vennesland, O., “Critical Chloride Content in Reinforced Concrete – A Review,” Cement and Concrete Research, 2009, Vol. 39, pp. 1122-1138.

7. Pettersson, K., “Chloride Threshold Value and the Corrosion Rate in Reinforced Concrete,” Proceedings of Concrete 2000, 1993, Vol. 1, E&FN Spon, p. 461.

8. Ann, K. Y., & Song, H., W., “Chloride Threshold Level for Corrosion of Steel in Concrete,” Corrosion Science, 2000, Vol. 49, No. 11, pp. 4113-4133.

9. Trejo, D., and Tibbits, C., “The Influence of SCM Type and Quantity on the Critical Chloride Threshold,” ACI SP-308—Chloride Thresholds and Limits for New Construction, 2016, pp. 1-20.

10. Alonso, M. C., and Sanchez, M., “Analysis of Variability of Chloride Threshold Values in the Literature,” Materials and Corrosion, 2009, Vol. 60, No. 8, pp. 631-637.

11. Angst, U., Elsener, B., Larsen, C.K., Vennesland, O., “Chloride Induced Reinforcement Corrosion: Electrochemical Monitoring of Initiation Stage and Chloride Threshold Values,” Corrosion Science, 2011, Vol. 53, pp. 1451-1464.

12. Thomas, M.D.A, “Chloride Thresholds in Marine Concrete,” Cement & Concrete Research, 1996, Vol. 26, No. 4, pp. 513-519.

13. Malhotra, V.M., Carette, G.G., and Bremner, T.W., “Current Status of CANMET’s Studies on the Durability of Concrete Containing Supplementary Cementing Materials in Marine Environment,” Proceedings of the Second Marine Environment, SP-109-2, V.M. Malhotra, ed., American Concrete Institute, St. Andrews by-the-Sea, Canada, 1988, pp. 31-72.

14. Andrade, C., and Gonzalez, J. A., “Quantitative Measurements of Corrosion Rate of Reinforcing Steels Embedded in Concrete Using Polarization Resistance Measurements,” Materials & Corrosion, 2009, V. 29, No. 8, pp .515–519.

15. Christensen, B. J., Coverdale, T., Olson, R. A., Ford, S. J., Garboczi, E. J., Jennings, H. M. and Mason, T. O., “Impedance Spectroscopy of Hydrating Cement-Based Materials: Measurement, Interpretation, and Application,” Journal of the American Ceramic Society, 1994, Vol. 77, pp. 2789–2804

16. John, D.G., Searson, P.C., Dawson, J.L., “Use of AC Impedance Technique in Studies on Steel in Concrete in Immersed Conditions,” Br. Corros. J., 1981, Vol. 16, No. 2, pp. 102-106

17. Ehlen, M.A., Thomas, M.D.A., and Bentz, E.C., “Life-365 Service Life Prediction Model Version 2.0,” Life-365 Consortium II, 2009, User Manual.

18. Andrade, C., “Calculation of Chloride Diffusion Coefficients in Concrete From Ionic Migration Measurements,” Cement and Concrete Research, 1993, Vol. 23, No. 3, pp. 724-742.

19. Samson, E., Marchand, J., & Snyder, K. A., “Calculation of Ionic Diffusion Coefficients on the Basis of Migration Test Results,” Materials and Structures, 2003, Vol. 36, No. 3, pp. 156-165.

20. Truc, O., Ollivier, J.P., and Carcasses, M., “A New Way for Determining the Chloride Diffusion Coefficient in Concrete from Steady-state Migration Test,” Cement and Concrete Research, 2000, Vol. 30, pp. 217-226.

21. Castellote, M., Andrade, C., & Alonso, C., “Chloride-Binding Isotherms in Concrete Submitted to Non-Steady-State Migration Experiments,” Cement and Concrete Research, 1999, Vol. 29, No. 11, pp. 1799-1806.

22. Scanlon, J. M., and Sherman, M. R., “Fly Ash Concrete: An Evaluation of Chloride Penetration Testing Methods,” Concrete International, 1996, Vol. 18, No. 6, pp. 57–62.

23. Wee, T. H., Suryavanshi, A. K., & Tin, S. S., “Evaluation of Rapid Chloride Permeability Test (RCPT) Results for Concrete Containing Mineral Admixtures,” ACI Materials Journal, 2000, Vol, 97, No. 2 pp. 221-232.

24. Yang, C.C., “Relationship between Migration Coefficient of Chloride Ions and Charge Passed in Steady State,” ACI Materials Journal, 2004, Vol. 101, No. 2, pp. 124-130.

25. Broomfield, J. P., “Corrosion of steel in concrete: Understanding, investigation, and repair,” London: E & FN Spon.3, 1997.

26. Alonso, C., Andrade, C., and Gonzalez, J., “Relation between resistivity and corrosion rate of reinforcements in carbonated mortar made with several cement types,” Cement and Concrete Research, 1988, Vol. 8, No. 5, pp. 687–698.

27. Lopez, W. and Gonzalez, J. A., “Influence of the degree of pore saturation on the resistivity of concrete and the corrosion rate of steel reinforcement,” Cement and concrete research, 1993, Vol. 23, No. 2, pp. 368–376.