Interfacial Transition Zone of Alkali-Activated Slag Concrete

International Concrete Abstracts Portal

The International Concrete Abstracts Portal is an ACI led collaboration with leading technical organizations from within the international concrete industry and offers the most comprehensive collection of published concrete abstracts.

  


Title: Interfacial Transition Zone of Alkali-Activated Slag Concrete

Author(s): Tao Ji, Qiaoling Gao, Wenyuan Zheng, Xujian Lin, and Hwai-Chung Wu

Publication: Materials Journal

Volume: 114

Issue: 3

Appears on pages(s): 347-354

Keywords: activator types; Ca/Si ratio; microhardness; presoaked ceramsite; sodium sulfate

DOI: 10.14359/51689473

Date: 5/1/2017

Abstract:
In this study, both micro and macro tests were performed to investigate the effect of activator types on the characteristics of the interfacial transition zone (ITZ) in alkali-activated slag concrete (AASC) with presoaked ceramsite. Two types of chemical activators (Na2SO4 and Na2SO4 plus water glass) were used, each leading to unique cement products. Microhardness was measured within ITZ and analyzed together with microstructure observations by scanning electron microscopy (SEM). Macroscopic properties, including compressive strength and splitting tensile strength, were also measured. For the AASCs with natural coarse aggregate and ceramsite activated by Na2SO4, the microhardness and the Ca/Si ratio of the ITZ are lower than that of portland-cement concrete (PC). For the natural coarse aggregate-AASC activated by Na2SO4 plus water glass, the microhardness of the ITZ is higher than that of PC, and the Ca/Si ratio of the ITZ is lower than that of PC; replacing natural coarse aggregate with ceramsite, the microhardness of the ITZ improves further.

Related References:

1. Juenger, M. C. G.; Winnefeld, F.; Provis, J. L.; and Ideker, J. H., “Advances in Alternative Cementitious Binders,” Cement and Concrete Research, V. 41, No. 12, 2011, pp. 1232-1243. doi: 10.1016/j.cemconres.2010.11.012

2. Gartner, E. M., and Macphee, D. E., “A Physico-Chemical Basis for Novel Cementitious Binders,” Cement and Concrete Research, V. 41, No. 7, 2011, pp. 736-749. doi: 10.1016/j.cemconres.2011.03.006

3. Ali, M. B.; Saidur, R.; and Hossain, M. S., “A Review on Emission Analysis in Cement Industries,” Renewable & Sustainable Energy Reviews, V. 15, No. 5, 2011, pp. 2252-2261. doi: 10.1016/j.rser.2011.02.014

4. Provis, J. L., and Van Deventer, J. S. J., eds., Geopolymers: Structures, Processing, Properties and Industrial Applications, Woodhead/Elsevier, Cambridge, MA, 2009.

5. Li, C.; Sun, H.; and Li, L., “A Review: The Comparison between Alkali-Activated Slag (Si + Ca) and Metakaolin (Si + Al) Cements,” Cement and Concrete Research, V. 40, No. 9, 2010, pp. 1341-1349. doi: 10.1016/j.cemconres.2010.03.020

6. Shi, C. J.; Kriver, P. V.; and Roy, D., Alkali-Activated Cements and Concretes, Taylor & Francis, New York, 2006.

7. Pu, X. C., Alkali Activated Cement and Concrete, SciPress, Beijing, China, 2010.

8. Deja, J., “Carbonation Aspects of Alkali Activated Slag Mortars and Concretes,” Silicates Industriels, V. 3-4, 2002, pp. 37-42.

9. Chandra, S., and Berntsson, L., Lightweight Aggregate Concrete: Science, Technology, and Applications, William Andrew, Norwich, NY, 2002.

10. Akcay, B., and Tasdemir, M. A., “Optimisation of Using Lightweight Aggregates in Mitigating Autogenous Deformation of Concrete,” Construction and Building Materials, V. 23, No. 1, 2009, pp. 353-363. doi: 10.1016/j.conbuildmat.2007.11.015

11. Sakulich, A. R., and Bentz, D. P., “Mitigation of Autogenous Shrinkage in Alkali Activated Slag Mortars by Internal Curing,” Materials and Structures, V. 46, No. 8, 2013, pp. 1355-1367. doi: 10.1617/s11527-012-9978-z

12. Bentz, D. P., and Weiss, W. J., “Internal Curing: A 2010 State-of-the-Art Review,” U.S. Department of Commerce, National Institute of Standards and Technology, Washington, DC, 2011.

13. Wang, F. Z.; Zhou, B.; Peng, Y. Z.; and Hu, S. G., “Research on the Elements Distribution Characteristics in the Interfacial Transition Zone (ITZ) between Lightweight Aggregate and Cement Paste,” Journal of Wuhan University of Technology, V. 27, No. 3, 2005, pp. 30-33.

14. Bentz, D. P., “Influence of Internal Curing Using Lightweight Aggregates on Interfacial Transition Zone Percolation and Chloride Ingress in Mortars,” Cement and Concrete Composites, V. 31, No. 5, 2009, pp. 285-289. doi: 10.1016/j.cemconcomp.2009.03.001

15. Bondar, D.; Lynsdale, C. J.; and Milestone, N. B., “Alkali-Activated Natural Pozzolan Concrete as New Construction Material,” ACI Materials Journal, V. 110, No. 3, May-June 2013, pp. 331-337.

16. Cheng, Y. Z., “Research on Neutral Sodium Salt Alkali-Activated Slag Cement and Concrete,” doctoral thesis, Chongqing Build University, Chongqing, China, 1998.

17. GB/T17431-2-1998, “Lightweight Aggregate and Its Test Method—Part 2: Test Methods for Lightweight Aggregates,” China Building Industry Press, Beijing, China, 1998.

18. GB/T14684-2001, “Sand for Building,” China Building Industry Press, Beijing, China, 2001.

19. JGJ55-2011, “Specification for Mix Proportion Design of Ordinary Concrete,” China Building Industry Press, Beijing, China, 2011.

20. JGJ51-2002, “Technical Specification for Lightweight Aggregate Concrete,” China Building Industry Press, Beijing, China, 2002.

21. Cheng, X. F., “Early Age Autogenous Shrinkage of Lightweight Aggregate Concrete,” master’s thesis, Fuzhou University, Fuzhou, China, 2011.

22. Ji, T.; Chen, C. Y.; Zhuang, Y. Z.; and Lin, X. J., “Effect of Degree of Ceramsite Prewetting on the Cracking Behaviour of LWAC,” Magazine of Concrete Research, V. 64, No. 8, 2012, pp. 687-695. doi: 10.1680/macr.11.00128

23. Cheng, Y. B., “Study of influence of Ceramsite Characteristics on Lightweight Aggregate Concrete Cracking Resistant Performance,” master’s thesis, Fuzhou University, Fuzhou, China, 2010.

24. GB/T50080-2002, “Standard for Test Method of Performance on Ordinary Concrete Mixture,” China Building Industry Press, Beijing, China, 2003.

25. GB/T50081-2002, “Standard for Test Method of Mechanical Properties on Ordinary Concrete,” China Building Industry Press, Beijing, China, 2003.

26. Aligizaki, K. K., Pore Structure of Cement-Based Materials: Testing, Interpretation and Requirements, CRC Press, Boca Raton, FL, 2005.

27. Wu, H. C., and Sun, P., “On Sol-Gel Approach to Geopolymerisation,” International Journal of Environmental Engineering, V. 3, No. 2, 2011, pp. 103-122. doi: 10.1504/IJEE.2011.039449

28. Zheng, W. Y., “Study on the Interfacial Transition Zone of Alkali-Activated Slag Ceramsite Concrete,” master’s thesis, Fuzhou University, Fuzhou, China, 2015.

29. He, Y.; Lu, L.; Struble, L. J.; Rapp, J. L.; Mondal, P.; and Hu, S., “Effect of Calcium-Silicon Ratio on Microstructure and Nanostructure of Calcium Silicate Hydrate Synthesized by Reaction of Fumed Silica and Calcium Oxide at Room Temperature,” Materials and Structures, V. 47, No. 1-2, 2014, pp. 311-322. doi: 10.1617/s11527-013-0062-0


ALSO AVAILABLE IN:

Electronic Materials Journal



  

Edit Module Settings to define Page Content Reviewer