Viscoelastic Behavior of Silica Fume in Absence of Binder

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Title: Viscoelastic Behavior of Silica Fume in Absence of Binder

Author(s): Shuang Lu and D. D. L. Chung

Publication: Materials Journal

Volume: 112

Issue: 1

Appears on pages(s): 137-146

Keywords: bulk density; cement; compaction; dynamic loading; modulus; silica fume; vibration

DOI: 10.14359/51686983

Date: 1/1/2015

Abstract:
The viscoelastic behavior of silica fume (with and without silane treatment) without a binder is evaluated under dynamic smallstrain compression. The loss-tangent/solid-content, storagemodulus/solid-content, and loss-modulus/solid-content describe the solid part of the compact; they increase with silane treatment, and decrease with increasing frequency. The viscous character stems from the interparticle movement. The highest loss-tangent/solid-content is 0.57 and 0.41 for treated and untreated silica fume, respectively; the highest storage-modulus/solid-content is 24 and 12 psi (165 and 82 kPa) for treated and untreated silica fume, respectively. The treatment results in increased aggregation, ≤40% increase in the loss-tangent/solid-content (due to the viscous character of silane), ≤90% increase in the storage-modulus/solidcontent(due to the increased cohesion), and ≤180% increase in the loss-modulus/solid-content. An increase in the solid content of the silane-treated silica fume results in a decrease in the loss-tangent/solid-content (due to the decreasing ease of interparticle movement), but an increase in the storage-modulus/solid-content (due to increased cohesion).

Related References:

1. Bagheri, A. R.; Zanganeh, H.; and Moalemi, M. M., “Mechanical and Durability Properties of Ternary Concretes Containing Silica Fume and Low Reactivity Blast Furnace Slag,” Cement and Concrete Composites, V. 34, No. 5, May 2012, pp. 663-670.

2. Chen, P., and Chung, D. D. L., “Mechanical Energy Dissipation Using Cement-Based Materials with Admixtures,” ACI Materials Journal, V. 110, No. 3, May-June 2013, pp. 279-290.

3. Chung, D. D. L., “Improving Cement-Based Materials by Using Silica Fume,” Journal of Materials Science, V. 37, No. 4, Feb. 2002, pp. 673-682.

4. Xu, Y., and Chung, D. D. L., “Cement-Based Materials Improved by Surface Treated Admixtures,” ACI Materials Journal, V. 97, No. 3, May-June 2000, pp. 333-342.

5. Xu, Y., and Chung, D. D. L., “Improving Silica Fume Cement by Using Silane,” Cement and Concrete Research, V. 30, No. 8, Aug. 2000, pp. 1305-1311.

6. ACI Committee 234, “Guide for the Use of Silica Fume in Concrete (ACI 234R-06),” American Concrete Institute, Farmington Hills, MI, 2006, 63 pp.

7. Xu, Y., and Chung, D. D. L., “Silane-Treated Carbon Fiber for Reinforcing Cement,” Carbon, V. 39, No. 13, 2001, pp. 1995-2001.

8. Liu, T., and Ou, J., “Effects of Silane-Treated Silica Fume on Damping Property of Cement Mortar,” Proceedings RILEM, PRO 32, V. 1, 2003, pp. 168-176.

9. Shokoohi, S.; Arefazar, A.; and Khosrokhavar, R., “Silane Coupling Agents in Polymer-Based Reinforced Composites: A Review,” Journal of Reinforced Plastics and Composites, V. 27, No. 5, Jan. 2008, pp. 473-485.

10. Chen, P., and Chung, D. D. L., “Dynamic Mechanical Properties of Flexible Graphite Made from Exfoliated Graphite,” Carbon, V. 50, No. 1, Jan. 2012, pp. 283-289.

11. Yanagida, T.; Matchett, A. J.; and Coulthard, J. M., “Damping and Elastic Properties of Binary Powder Mixtures,” Powder Technology, V. 127, No. 2, Oct. 2002, pp. 107-115.

12. Yanagida, T.; Matchett, A.; Asmar, B.; Langston, P.; Walters, K.; and Coulthard, M., “Damping Characterization of Particulate Materials Using Low Intensity Vibrations: Methodology for Determining Damping Properties from Acceleration Transmissivity Data and Comparison with Existing Direct Experimental Techniques,” Journal of Chemical Engineering of Japan, V. 36, No. 11, June 2004, pp. 1327-1338.

13. ASTM D4065-12, “Standard Practice for Plastics: Dynamic Mechanical Properties: Determination and Report of Procedures,” ASTM International, West Conshohocken, PA, 7 pp.


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