Title:
Portland Limestone Cement Concrete Incorporated with Clay Pozzolana (Prepublished)
Author(s):
Mark Bediako and Timothy Kofi Ametefe
Publication:
Materials Journal
Volume:
Issue:
Appears on pages(s):
Keywords:
carbon-chloride penetration index; carbon-strength index; clay pozzolana; environmental impact assessment; Portland limestone cement; thermodynamic modelling
DOI:
10.14359/51749251
Date:
10/8/2025
Abstract:
Portland Limestone Cement (PLC) has gained widespread use as the most accessible and sustainable blended cement in the market. However, in many African countries, including Ghana, the use of clay pozzolana in the concrete industry has primarily relied on Ordinary Portland Cement (OPC). In this study, PLC Type II/B-L was partially replaced with clay pozzolana at levels ranging from 10% to 50% by weight. The investigation included compressive strength testing, non-destructive evaluations using electrical surface resistivity, pulse velocity, and chloride penetration tests, targeting a characteristic strength of 30 MPa. Additionally, an environmental impact assessment based on the carbon footprint of both control and clay pozzolana concretes was conducted. The mix design followed the EN 206 standard. A total of 72 cubic moulds were produced for the strength test. The results showed that clay pozzolana concretes with between 10 and 20% replacement achieved strength values of 35 and 33 MPa, respectively, higher than the target of 30 MPa (4351.13 psi) strength at 28 days. However, mixtures with 30% to 50% replacement required extended curing periods of 60 to 90 days to reach the desired strength. At extended curing, 10-50% clay pozzolana replacement attained strength between 32 and 41 MPa. Non-destructive test results showed no direct correlation with compressive strength, confirming that different factors govern strength, resistivity, and pulse velocity. The environmental impact assessment revealed a 14 to 51% reduction in CSi and a 19 to 36% increase in CRi with 10 to 50% clay pozzolana (for CSi) and 10 to 40% (for CRi). The thermodynamic modelling also revealed that pozzolana contents below 30% primarily promoted pozzolanic reactions, enhancing performance compared to the control mix. Based on these results, 20–30% clay pozzolana replacement is recommended to ensure reliable performance, while higher levels (>30%) require further durability evaluation for long-term use.