Graphene Oxide as Additive to Replace Using Air-Entraining Agents

International Concrete Abstracts Portal

The International Concrete Abstracts Portal is an ACI led collaboration with leading technical organizations from within the international concrete industry and offers the most comprehensive collection of published concrete abstracts.

  


Title: Graphene Oxide as Additive to Replace Using Air-Entraining Agents

Author(s): Alyaa Mohammed, Jay Sanjayan, Ali Nazari, Nihad T. K. Al-Saadi, and Wenhui Duan

Publication: Materials Journal

Volume: 114

Issue: 6

Appears on pages(s): 859-866

Keywords: air content; freezing and thawing; graphene oxide; microcrack; nitrogen adsorption

DOI: 10.14359/51700990

Date: 11/1/2017

Abstract:
Despite its negative impact on compressive strength of concrete, practitioners rely exclusively on using air entrainment to defeat freezing-and-thawing deterioration. This paper describes the use of graphene oxide (GO) as an effective method to minimize the negative impact of freezing-and-thawing action in concrete while maintaining high compressive strength. Two series of graphene oxidebearing concrete samples (containing 0.01% and 0.06% graphene oxide by cement weight) were produced. Plain concrete samples and samples with 4% air-entraining content were also produced for comparison. All the concrete samples were subjected to up to 500 repeated freezing-and-thawing cycles. Different series of tests such as electric resistance, nitrogen adsorption, and compressive strength were conducted within and at the end of the freezing-andthawing cycles. The results show that the GO specimens indicate higher initial compressive strength than the control and the air-entrained specimens. A significant enhancement of freezingand-thawing resistance in the graphene oxide-bearing concrete samples was expressed in maintaining the compressive strength close to initial values before the exposure to freezing-and-thawing cycles.

Related References:

1. Cai, H., and Liu, X., “Freeze-Thaw Durability of Concrete: Ice Formation Process in Pores,” Cement and Concrete Research, V. 28, No. 9, 1998, pp. 1281-1287.

2. Neville, A. M., Properties of Concrete, Pearson Education, United Kingdom, 2012.

3. Ansari, F.; Zhang, Z.; Luke, A.; and Maher, A., “Effects of Synthetic Air Entraining Agents on Compressive Strength of Portland Cement Concrete-Mechanism of Interaction and Remediation Strategy,” Final Report FHWA-NJ-2002-025, July 2000.

4. Rao, C., and Ardani, A., “Concrete Deck Performance Relative to Air Entrainment,” Final Report, Colorado Department of Transportation, Denver, CO, 2009.

5. Suk, J. W.; Piner, R. D.; An, J.; and Ruoff, R. S., “Mechanical Properties of Monolayer Graphene Oxide,” ACS Nano, V. 4, No. 11, 2010, pp. 6557-6564. doi: 10.1021/nn101781v

6. Cano, M.; Khan, U.; Sainsbury, T.; O’Neill, A.; Wang, Z.; and McGovern, I. T., “Improving the Mechanical Properties of Graphene Oxide Based Materials by Covalent Attachment of Polymer Chains,” Carbon, V. 52, No. 2, 2013, pp. 363-71.

7. Dreyer, D. R.; Todd, A. D.; and Bielawski, C. W., “Harnessing the Chemistry of Graphene Oxide,” Chemical Society Reviews, V. 43, No. 15, 2014, pp. 5288-5301. doi: 10.1039/C4CS00060A

8. Sanchez, F., and Sobolev, K., “Nanotechnology in Concrete—A Review,” Construction and Building Materials, V. 24, No. 11, 2010, pp. 2060-2071. doi: 10.1016/j.conbuildmat.2010.03.014

9. Compton, O. C., and Nguyen, S. T., “Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials,” Small, V. 6, No. 6. 2010, pp. 711-723.

10. Singh, V.; Joung, D.; Zhai, L.; Das, S.; Khondaker, S. I.; and Seal, S., “Graphene Based Materials: Past, Present and Future,” Progress in Materials Science, V. 56, No. 8, 2011, pp. 1178-1271. doi: 10.1016/j.pmatsci.2011.03.003

11. Chen, D.; Feng, H.; and Li, J., “Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications,” Chemical Reviews, V. 112, No. 11, 2012, pp. 6027-6053. doi: 10.1021/cr300115g

12. Rhee, I.; Kim, Y. A.; Shin, G.-O.; Kim, J. H.; and Muramatsu, H., “Compressive Strength Sensitivity of Cement Mortar Using Rice Husk-Derived Graphene with a High Specific Surface Area,” Construction and Building Materials, V. 96, 2015, pp. 189-97.

13. Pan, Z.; He, L.; Qiu, L.; Korayem, A. H.; Li, G.; Zhu, J. W.; Collins, F.; Li, D.; Duan, W. H.; and Wang, M. C., “Mechanical Properties and Microstructure of a Graphene Oxide-Cement Composite,” Cement and Concrete Composites, V. 58, 2015, pp. 140-147. doi: 10.1016/j.cemconcomp.2015.02.001

14. Mohammed, A.; Sanjayan, J.; Duan, W.; and Nazari, A., “Incorporating Graphene Oxide in Cement Composites: A Study of Transport Properties,” Construction and Building Materials, V. 84, 2015, pp. 341-347.

15. Kosmatka, S. H., and Panarese, W. C., “Design and Control of Concrete Mixtures,” Portland Cement Association, Skokie, IL, 2002.

16. Mohammed, A.; Sanjayan, J.; Duan, W.; and Nazari, A., “Graphene Oxide Impact on Hardened Cement Expressed in Enhanced Freeze-Thaw Resistance,” Journal of Materials in Civil Engineering, ASCE, V. 28, No. 9, 2016, p. 04016072. doi: 10.1061/(ASCE)MT.1943-5533.0001586

17. AS 3972-2010, “General Purpose and Blended Cements,” Committee BD-010, Cement, https://infostore.saiglobal.com/store/PreviewDoc.aspx?saleItemID=2178074. (last accessed Nov. 3, 2017)

18. ACI Committee 201, “Guide to Durable Concrete (ACI 201.2R-08),” American Concrete Institute, Farmington Hills, MI, 2008, 16 pp.

19. ASTM C231/C231M-14, “Standard Test Method for Air Content of Freshly Mixed Concrete by the Pressure Method,” ASTM International, West Conshohocken, PA, 2014, 9 pp.

20. ASTM C666/C666M-03, “Standard Test Method for Resistance of Concrete to Rapid Freezing and Thawing,” ASTM International, West Conshohocken, PA, 2003, 7 pp.

21. De Belie, N.; Kratky, J.; and Van Vlierberghe, S., “Influence of Pozzolans and Slag on the Microstructure of Partially Carbonated Cement Paste by Means of Water Vapour and Nitrogen Sorption Experiments and BET Calculations,” Cement and Concrete Research, V. 40, No. 12, 2010, pp. 1723-1733. doi: 10.1016/j.cemconres.2010.08.014

22. Brunauer, S.; Emmett, P. H.; and Teller, E., “Adsorption of Gases in Multimolecular Layers,” Journal of the American Chemical Society, V. 60, No. 2, 1938, pp. 309-319. doi: 10.1021/ja01269a023

23. ASTM C39/C39M-15a, “Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens,” ASTM International, West Conshohocken, PA, 2015, 7 pp.

24. ASTM C457/C457M-12, “Standard Test Method for Microscopical Determination of Parameters of the Air-Void System in Hardened Concrete,” ASTM International, West Conshohocken, PA, 2012, 18 pp.

25. Alexander, M., “Engineering and Transport Properties of the Interfacial Transition Zone in Cementitious Composites,” Rilem Publications, V. 20, France, 1999, pp. 310-316.

26. Qu, F., and Niu, D. T., “Effect of Freeze-Thaw on the Concrete Pore Structure Features,” Advanced Materials Research, V. 368-373, 2012, pp. 361-364.

27. Cohen, M. D.; Zhou, Y.; and Dolch, W. L., “Non-Air-Entrained High-Strength Concrete—Is It Frost Resistant?” ACI Materials Journal, V. 89, No. 4, July-Aug. 1992, pp. 406-415.

28. Soroushian, P., and Elzafraney, M., “Damage Effects on Concrete Performance and Microstructure,” Cement and Concrete Composites, V. 26, No. 7, 2004, pp. 853-859.

29. Lindqvist, J.; Åkesson, U.; and Malaga, K., “Microstructure and Functional Properties of Rock Materials,” Materials Characterization, V. 58, No. 11, 2007, pp. 1183-1188. doi: 10.1016/j.matchar.2007.04.012

30. Cote, L. J.; Kim, J.; Tung, V. C.; Luo, J.; Kim, F.; and Huang, J., “Graphene Oxide as Surfactant Sheets,” Pure and Applied Chemistry, V. 83, No. 1, 2010, pp. 95-110. doi: 10.1351/PAC-CON-10-10-25

31. Powers T. C., “A Working Hypothesis for Further Studies of Frost Resistance of Concrete,” ACI Journal Proceedings, V. 41, No. 1, Jan. 1945, pp. 245-272.

32. Pigeon, M.; Marchand, J.; and Pleau, R., “Frost Resistant Concrete,” Construction and Building Materials, V. 10, No. 5, 1996, pp. 339-348.

33. ACI Committee 318, “Building Code Requirements for Structural Concrete (ACI 318-14) and Commentary (ACI 318R-14),” American Concrete Institute, Farmington Hills, MI, 520 pp.

34. BS 8500-1:2015, “Concrete. Complementary British Standard to BS EN 206. Method of Specifying and Guidance for the Specifier,” British Standards Institute, London, UK, 66 pp.

35. Zhu, J.; Andres, C. M.; Xu, J.; Ramamoorthy, A.; Tsotsis, T.; and Kotov, N. A., “Pseudonegative Thermal Expansion and the State of Water in Graphene Oxide Layered Assemblies,” ACS Nano, V. 6, No. 9, 2012, pp. 8357-8365. doi: 10.1021/nn3031244

36. Estevez, L.; Kelarakis, A.; Gong, Q.; Da’as, E. H.; and Giannelis, E. P., “Multifunctional Graphene/Platinum/Nafion Hybrids via Ice Templating,” Journal of the American Chemical Society, V. 133, No. 16, 2011, pp. 6122-6125.

37. Qiu, L.; Liu, J. Z.; Chang, S. L. Y.; Wu, Y.; and Li, D., “Biomimetic Superelastic Graphene-Based Cellular Monoliths,” Nature Communications, V. 3, 2012, 1241 pp.

38. Hyun, S., and Torquato, S., “Effective Elastic and Transport Properties of Regular Honeycombs for All Densities,” Journal of Materials Research, V. 15, No. 09, 2000, pp. 1985-1993. doi: 10.1557/JMR.2000.0285


ALSO AVAILABLE IN:

Electronic Materials Journal