International Concrete Abstracts Portal

Many of the papers presented in this volume were included in the two-part session Nanotechnology for Improved Concrete Performance, sponsored by ACI Committee 241, Nanotechnology of Concrete at the ACI Convention in Philadelphia, PA, on October 26, 2016. In line with the practice and requirements of the American Concrete Institute, peer review, followed by appropriate response and revision by authors, has been implemented.

A  detailed  microstructural  and  micromechanical  study  of  a  fly  ash‐based  geopolymer  paste  including: (i) synchrotron x‐ray tomography (XRT) to characterize the pores (size > 0.74 m) that are influential in fluid transport, (ii) mercury intrusion porosimetry (MIP) to capture the volume fraction of smaller  pores,  (iii)  high  resolution  scanning  electron  microscopy  (SEM)  combined  with  a  multi‐label  thresholding method to identify and characterize the solid phases in the microstructure, and (iv) nanoindentation  to  determine  the  component  phase  elastic  properties  using  statistical  deconvolution  techniques, is reported in this paper. The 3D pore structure from XRT is used in a computational fluid transport  model  to  predict  the  permeability  of  the  material.  The  pore  volume  from  XRT,  solid  phase  volumes from SEM, and the phase elastic properties are used in a numerical homogenization framework to determine the homogenized macroscale elastic modulus of the composite. The homogenized elastic moduli are in good agreement with the flexural elastic modulus determined on macroscale paste beams. It  is  shown  that  the  combined  use  of  microstructural  and  micromechanical  characterization  tools  at  multiple scales provides valuable information towards the material design of fly ash‐based geopolymers.

In this study, nanosilica was applied to the surface of polypropylene (PP) fibers to introduce self-healing abilities when incorporated into cement-composites. When the fiber is at the site of a crack, the nanosilica can form additional hydration products through pozzolanic reaction to effectively seal the crack. Nanosilica was synthesized onto the fibers through a sol-gel process. Then the fibers were dried at room temperature or 50°C (122°F) to remove the excess solution and adhere the nanosilica particles onto the fiber surface. The existence of nanosilica was confirmed by observing the mass change before and after the sol-gel process, water absorption, soluble matter loss and microscopy. The self-healing performance of cement-composites reinforced with treated and untreated macro and micro PP fibers at dosages of 1.8kg/m3 (3.0lb/yd3) and 0.9kg/m3 (1.5lb/yd3), respectively, were evaluated through flexural strength testing according to ASTM C348. To evaluate strength recovery, samples were loaded to 60% of the peak load to induce cracking. The cracked specimens were cured for 28 days under laboratory conditions to undergo self-healing. A significant recovery in flexural strength (112.8%) was observed by using nanosilica treated micro PP fibers dried at room temperature.

In this work, effects of nanosilica (NS), nanolimestone (NL), and nanoclay (NC) additions on hydration and strength of cement pastes were studied. The pastes were made with Type I ordinary Portland cement (OPC), 0 and 30% Class F fly ash (FA), and 0 or 1% nanomaterials. All pastes had a water-to-binder ratio of 0.5. Chemical shrinkage was monitored as an indication of cement hydration process. X-ray diffraction (XRD) was conducted to identify crystalline hydration products. Thermogravimetric analysis (TGA) was used to quantify calcium hydroxide (CH) and chemically bound water. The results indicate that the rate of chemical shrinkage curve can be divided into five stages, similar to that observed from the rate of cement hydration curve measured from a calorimetry test. All nanomaterials increased the rate of chemical shrinkage associated with C3S and C2S reactions; but different types of nanomaterials had different effects on the rate of chemical shrinkage associated with secondary C3A reaction. All nanomaterials improved strength of OPC paste at ages up to 28 days; but the improvement was not clear for OPCFA pastes. Through reaction with OPC and FA, NL stabilized voluminous ettringite and produced hemicarbonate (Hc) instead of less voluminous monosulfate (Ms).

Due to the ubiquity of concrete in the urban environment and the upscaling of nanomaterial production, the incorporation of nanoparticles into cementitious materials has gained increased attention. This study compares the performance of various titania (TiO₂) and silica (SiO₂) nanoparticles-modified coatings, including their photocatalytic performance and the quality of their adhesion to the cementitious substrates. The photocatalytic performance with respect to air purification and self-cleaning are evaluated by nitrogen oxide (NO_x) and methylene blue (MB) dye photodegradation, respectively. The results show that the Portland cement (OPC)-based cementitious materials exhibit greater photocatalytic efficiency than calcium aluminate cement (CAC)-based ones. It is proposed that the superior performance is due to a greater proportion of finer porosity and the presence of high surface area calcium silicate hydrates (C-S-H) in OPC-based cementitious materials. Interactions between coatings and cementitious substrates are examined through wettability and adhesion. The results show that the inclusion of silica layer can affect the interaction of coated cementitious surface with water, as well as the bond strength between coating and cementitious substrate.