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Chloride-induced corrosion is a problem common to steel reinforced concrete exposed to chloride ions. A severe case is the use of reinforced concrete in seawater. The high-chloride concentration in salt water, the geometry of concrete piles, and the moisture differential between concrete above and below the water line are all factors that complicate the problem. The corrosion resistance of steel reinforced concrete is a function of the concrete cover of the steel, concrete permeability, surface chloride concentration, and ambient temperature. In this paper, the authors present diffusion curves for chloride ingress into concrete piles. The diffusion coefficients are based on extensive laboratory and field studies. They also discuss the usefulness of this model, based on Fick's law of diffusion. By estimating the chloride ion concentration at the steel reinforcement after a given amount of time, the lifetime of the structure can be predicted. In addition to concrete quality, concrete admixtures affect the corrosion of steel in concrete. Two concrete admixtures are discussed--calcium nitrite and microsilica. As demonstrated in other publications, both of these additives delay the onset of corrosion. It has also been shown that calcium nitrite affects the rate of corrosion upon initiation. The appropriate dosage of each admixture can be determined using the chloride diffusion curves. Examples are described in the paper.

When anaerobic conditions occur in a sewer pipe in the presence of sulfate, sulfur-reducing bacteria will produce hydrogen sulfide. As hydrogen sulfide is released, various populations of sulfur-oxidizing bacteria (thiobacilli), will proliferate. The proliferation of these organisms results in a decrease in pH due to the production of sulfuric acid. Different thiobacilli will be present depending on the pH of the environment. Samples from regions of deteriorated and nondeteriorated concrete pipe were taken to determine the presence of microorganisms that could cause microbially induced concrete deterioration. The results presented show that the degree of concrete deterioration can be correlated with the number and type of thiobacilli present. Extensive deterioration was observed at the crown of reinforced and asbestos concrete pipe, where the most acidophilic group of thiobacilli were present in elevated numbers. Areas of lesser deterioration were somewhat acidic, with a combination of different sulfur-oxidizing thiobacilli present. Areas that did not appear to be deteriorated were populated with the least acidophilic group of sulfur-oxidizing thiobacilli. The presence of microbially induced deterioration of concrete and the stage of deterioration can be determined by utilizing selective media to culture the various groups of sulfur-oxidizing bacteria associated with concrete decay.

An investigation was conducted to assess the structural integrity of a 17-year-old precast prestressed concrete conveyor bridge used to transport sodium chloride rock salt from a storage building to an outside stockpile area. The stockpile, depending on storage requirements, quite often buried most of the structure and/or subjected it to sodium chloride dust. The investigation revealed that the structure had performed remarkably well, considering the small concrete cover used to protect the reinforcing elements and the inadequate consideration of structural cracking induced by unanticipated loading from stockpiled salt. The concrete strength of the single tee members was estimated to be 7000 psi (48 MPa), with cover to the stirrups varying from virtually 0 to 1 1/2 in. (0 to 38 mm) and cover to the prestressing strands varying from 3/4 to 2 in. (19 to 51 mm). It was observed that aggressive prestressing strand corrosion causing pitting and some brittle wire failures occurred locally at flexural crack locations in single tee column members with little corrosion activity immediately adjacent to the cracks, even after 17 years of aggressive chloride exposure. This observation seems to conflict with the prevailing theory of the role of cracking on corrosion--that cracks perpendicular to steel reinforcement should result in limited early localized corrosion but, with time, chloride ions penetrate even uncracked concrete and initiate widespread corrosion.

Some properly proportioned portland cement-concrete mixtures occasionally show distress when exposed to freezing and thawing, while some mixtures that do not contain entrained air may appear to perform adequately despite exposure to freezing and thawing. Obviously, there is a difference in the severity of freezing-and-thawing environments. The factors affecting the severity of freezing-and-thawing environments include the temperature and moisture conditions and salt exposure. These factors are examined, along with materials properties that relate to these factors. Comparisons are made between laboratory and field moisture and thermal conditions, and the damage mechanisms most appropriate for each set of conditions are discussed. Conclusions are drawn concerning the definition of a truly severe freezing-and-thawing environment in the field, and a qualitative relationship between the severity of freezing-and-thawing environments and cooling rates is proposed.

Twenty roller-compacted concrete loads were cast at St. Constant near Montreal during the fall of 1987. Three types of cement (Canadian Types 10, 30, and 10SF), four different aggregate gradings, and three water-cement ratios (0:27, 0:33, and 0:35) were used to prepare the various mixes. Most of these mixes contained an air-entraining admixture. Approximately one-third of each concrete surface was moist-cured for 7 days, another third was covered with a white curing compound, and the remaining portion was not cured at all. Samples representative of all mixes and all curing conditions were taken from the pavement after 28 days and then tested for freeze-thaw durability (ASTM C 666) and deicer salt scaling resistance (ASTM C 672). The characteristics of the air-void system of all concretes were determined in accordance with ASTM C 457. With no exception, all samples withstood, without any significant deterioration, 300 cycles of freezing and thawing in water. However, the loss of mass after 50 cycles in the presence of a deicer salt solution ranged between 2 and 18 kg/mý (i.e., higher than the usual 1 kg/mý limit in all cases), even if most of the spacing factor values were below 250 æm. The best results (a weight loss of approximately 2 kg/mý after 50 cycles) were obtained for a mix containing Type 10 cement and no air-entraining admixture. In addition, this mix was not cured at all. Overwoking of the concrete surface during compaction is considered to be one of the possible explanations for the discrepancy between the results of the C 666 and the C 672 tests. It is also possible that the relationship between spacing factor and freeze-thaw durability does not apply to such concretes with a high permeability, numerous irregularly shaped compaction air voids, and large porous zones in the paste. This series of tests is the first phase of a 3-year research project on roller-compacted concrete pavements at Laval University, in collaboration with Canada Cement Lafarge. In the second and third years of this project, various ways to improve the scaling resistance (mostly by micro structural changes) will be studied.