International Concrete Abstracts Portal

Red mud is a by-product from the aluminum industry. To investigate the possibility of using this waste material as a pozzolan in the cement and concrete industries, tests were carried out to examine the pozzolanic properties of calcined red mud. Red mud was calcined for 5 hr at five different temperatures: 600, 650, 700, 750, and 800 C. Blended portland cements containing 30 or 50 percent of the calcined red mud were studied for hydration products, strength, and durability. The results indicated that the red mud had the maximum reactivity when calcined at 600 C, because on hydration the lime content of the blended cement was considerably reduced. The calcined red mud when used in combination with portland cement contributed to the formation of hydrated alumina-silicates and hydrogarnets. Very good compressive strengths were obtained with the blended cement containing 30 percent calcined red mud. Mortars cast with these blended cements were placed in solutions of seawater and acetic acid. The results indicated good stability of mortars to these environments.

29Si NMR has been employed as a tool to characterize the reaction mechanism of hydration in several blended cements up to 6 to 9.5 months. The cements investigated were blends with silica fume, fly ash, activated kaolinite, and blast furnace slag. Spectra deconvolution indicated that, in the silica fume as well as in the activated kaolinite blend, the reaction of the anhydrous calcium-silicates is initially accelerated with respect to the ordinary portland cement. In the fly ash blends, this effect is smaller. Both in the silica fume and fly ash blends, an increase in the amount of silica middle groups (Qý-type) at - 84 ppm, relative to the amount of silica end groups (Q1-type) at - 79 ppm, is notable, which indicates an increased tendency to form longer CSH chains. The size distribution and glass content of the fly ashes used seem to influence the hydration reaction, which is reflected by somewhat higher Qý/Qý ratios and an increased initial hydration. In the blends with activated kaolinite, it was not possible to deconvolute the Q1 and Qý chemical shifts at all ages, due to changes in the shift maxima Q1 and/or Qý. This may be due to the formation of amorphous noncrystalline alumina-containing reaction products. The chemical shift of the blast furnace slag appeared too broad for a successful deconvolution. In general, both the total (Q1 + Qý) as well as the Qý/Q1 ratio correlate with compressive strength data, Qý species contributing markedly. Paper contains a general overview of the application of NMR spectroscopy in cement and concrete research.

It is well known that curing concrete at elevated temperatures reduces the final compressive strength. The reduction depends on the temperature regime as well as the concrete composition. This program was based on recent data indicating that concrete containing condensed silica fume suffers less strength loss if a strength of about 10 MPa is reached at 20 C before heating. In this investigation, concrete characteristics were w/c + s = 0.30, 0.45, and 0.60 with and without 8 percent condensed silica fume. The temperature regime was to transfer specimens at 40 and 60 C, after delay times at 20 C. The delay times corresponded to strengths of about, 0, 3, 6, 9, 12, and 16 MPa. After 6 days, all specimens were cooled to 20 C and tested at 28d. The results show that the delay period had no significant influence on the final strength, except for the specimens with zero delay. The rest suffered some strength reduction compared to 20 C references, about 15 percent for w/c + s = 0.60, and less than 10 percent for the others. The reductions at 60 C were slightly greater than at 40 C. Concretes containing condensed silica fume generally suffered the smallest strength reductions.

In normal strength concretes, the compressive strength is limited by the strength of the binder and the binder-aggregate bond. In high-strength concretes, however, the binder strength and the bond may be fully comparable to the strength of the aggregate. This fact may lead to the conclusion that the strength of high-strength concretes may be improved by replacing an ordinary aggregate type with a high-strength aggregate. A number of aggregate types have been combined with high-strength binders to evaluate the impact of the aggregate strength on concrete compressive strength. The significance of the aggregate strength has been compared with the effect of the cement type and the use of silica fume. According to the obtained results, the impact of the aggregate strength on the strength of high-strength concrete is limited, compared to the binder type, while the difference in E-moduli between the different aggregate types is fully reflected in the concrete E-moduli. This contradiction is explained by a hypothesis based on stress concentrations due to the difference in rigidity between the binder and aggregate.

The mechanical and structural properties of mortars containing silica fume were studied. Mortars containing 5 and 10 percent active silica additive were made. Mortars without silica fume (standard mortars) were also prepared. A first set of mortar specimens was cured entirely in water. A second set of mortars was cured in air. The third was immersed in water and then subjected to alternating cycles of storage in water and air. The results show a very close relation between the conditions of the mortars' curing and their mechanical properties. The flexural strengths of mortars containing silica fume, subjected to variable curing conditions, show periodic increases and reductions. SEM observations confirmed the relations found in the flexural strength tests.