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With special attention to durability of concrete, the author reviewed the proceedings of the cement chemistry congresses as well as other symposia held during the last 50 years by ACI, ASTM, and RILEM. What is presented here is not a comprehensive progress report on the subject of concrete durability but rather a state-of-the-art report from the author's perspective. It seems that, in spite of some important discoveries valuable from the standpoint of durability enhancement, today more concrete structures seem to suffer from lack of durability than was the case 50 years ago. In order of decreasing importance, the major causes concrete deterioration today are as follows: corrosion of reinforcing steel, frost action in cold climates, and physico-chemical effects in aggressive environments. There is a general agreement that the permeability of concrete, rather than normal variations in the composition of portland cement, is the key to all durability problems. There is also a general agreement that rapid growth of the concrete construction industry after the 1940s led to the production and use of wet concrete mixtures, which are able to meet the strength requirement via a change in the composition of portland cement, but were unsatisfactory from the standpoint of corrosion of reinforcing steel, resistance to freezing and thawing cycles, and chemical attacks. A rise in chemical aggressivity of the environment through the increasing use of deicer salts, and an increase in land, water, and air pollution, has also contributed to concrete durability problems. Although significant advancements have been made in regard to understanding and controlling various physical and chemical phenomena responsible for concrete deterioration, the trend towards less durable concrete structures has yet to be reversed. One of the reasons is that most of the information from tests on durability is in fragmentary form and cannot be easily synthesized into a complete understanding of actual, long-term, effects on field concrete. An over-reliance on test methods and specifications dealing with different aspects of durability has therefore become a part of the problem since accelerated laboratory tests do not correlate well with behavior of concrete structures in practice.

Discusses the utilization of silica fume concrete admixture to prevent reinforcing steel corrosion. The mechanism of steel corrosion in salt-impregnated concrete is described, along with laboratory test date showing how ordinary concrete's corrosion-prone characteristics are altered by the use of silica fume. The mineral admixture significantly lowers the concrete permeability to prevent chloride ingress to the reinforcing steel level, while simultaneously increasing the concrete's electrical resistance to corrosion currents. Test data from the FHWA 90 day Chloride Ponding Test indicates a 98 percent reduction in chloride penetration. The AASHTO T277 rapid chloride permeability test shows a 10-times impermeability and 25-times resistivity improvement with the use of 12 percent silica fume. T he Time-to-Corrosion FHWA/NCHRP 244 slab test is scaled-down steel-reinforced deck, from which macrocell corrosion current, AC resistance, half-cell potential, and chloride absorption are measured. Zero corrosion current was measured after NaCl was ponded in alternate soak/dry cycles for 48 weeks. The second phase test program evaluated the corrosion performance of full-sized concrete bridge sections, including beams, columns, piles, and bridge deck panels. The test members were subjected to environments simulating salt water and deicing agents for 370 days. Test results show that silica fume admixture prevents salt-induced corrosion of steel a reinforcing bar and tensioning strands.

Corrosion of steel reinforcement within concrete structural elements is a major problem in both research and practice. Laboratory studies have been conducted on fundamental mechanisms of corrosion within concrete in the presence of high chloride and others under conditions of reduced alkalinity. However, little has been published on the interactive effects of these two conditions and the ways in which corrosion rates of steel in concrete are thereby influenced. These two conditions occur concurrently under many practical environmental exposures. This paper presents data on methodology used to determine corrosion rates of steel in concrete. Information on corrosion activities in both carbonated and high-chloride environments is presented with reference to mechanisms involved in breakdown of steel passivation. Interactive effects of the two conditions are examined for a range of concrete types and grades. The data suggest that for normal reinforced concrete structural elements, the interactive effects of carbonation and chloride ion ingress lead to much more rapid corrosion than where the two phenomena occur independently. The interactive effects of carbonation and chloride ions as they influence concretes under service conditions are discussed. In particular, the reduction of carbonation rate in the presence of high-chloride ion concentrations is noted.

The Canadian association of large public real estate companies has initiated a 5-year research project aimed at determining the most cost-effective way to rehabilitate deteriorated parking structures. A sample of 49 garages includes office, retail, and residential buildings. The repair history of each building has been documented and, in some cases, a formal condition survey of the garages is undertaken yearly. The collected data serve as a basis for the evaluation of the effectiveness of the various repair techniques and strategies. The project is now in its third year. The investigation was carried out concerning the excessive cracking noted in some garages constructed with epoxy-coated reinforcing steel. The benefits of intensive maintenance and good housekeeping have been shown by the analysis of the case history of a garage. Various types of concrete sealers have been evaluated by testing in the laboratory 57 products applied to 8 types of concrete substrate. Preliminary results indicate waterproofing membranes are an effective means to reduce the moisture content in the slab.

The durability in seawater of high-strength concretes produced with the addition of silica fume replacing a part of the cement was investigated. The influence of the wet-curing time on the behavior in seawater of high-strength mortars (strength in excess of 60 MPa) in which a part of the cement was replaced by densified silica fume, was determined. The various curing times applied to the specimens, after mold removal, were 48 hr, 7 days, and 28 days at 100 percent relative humidity, followed by storage for 28 days at 20 C and 50 percent relative humidity before the start of tests for resistance to seawater for 1 year. Investigation of the porosity of these mortars shows that, just after curing, the silica fume, as expected, reduces the total porosity of the reference mortar (25 to 45 percent) and substantially alters the pore-size distribution--the shorter the curing time, the more marked this effect. However, as hydration continues at 50 percent RH, the porosity of the reference mortar decreases and the differences in total porosity with respect to the mortars containing silica fume become smaller--the longer the initial curing time and the higher the C3 A content of the cement, the greater this effect. This explains the results of resistance to seawater, where it is found that silica fume contents of less than 10 percent do not lead to any significant improvement in behavior in seawater. This shows that the type of curing and the ambient conditions under which strength increases may limit the beneficial effects of silica fume on durability, when the addition of the silica fume is accompanied by a corresponding reduction of the cement content. It is also found that the best curing method is the specimens in fresh water for the first 7 days, while a curing time of only 48 hr is highly detrimental in terms of the subsequent behavior of the mortars in seawater.