International Concrete Abstracts Portal

Summarizes the work conducted by the Virginia Department of Transportation to evaluate the characteristics of concrete containing silica fume in the overlays as a protective system to prevent the penetration of chlorides into concrete. The first three field installations of silica fume concrete overlays in Virginia are described. The practices of other states in the USA for low-permeability silica fume concretes are also compared. The results indicate that silica fume concretes can be placed successfully in thin overlays on bridge decks. These concretes can provide the low permeabilities required to prevent the penetration of chlorides and other detrimental solutions into the concrete. Adherence to good construction practices is necessary, especially for the prevention of plastic shrinkage cracking.

In the case of high-strength concrete, the problem of temperature rise due to hydration is compounded, where the unit cement content is much higher than that encountered in normal concrete. This study was carried out to determine whether the merits of slag and silica fume addition could be combined to develop a low-heat high-strength concrete, in which the heat generation can be controlled by blending the cementitious constituents, keeping the compressive strength about 80 MPa (at 91 days). The program was divided into two phases, using mortar in the first phase to study the effect of partial replacement of cement by slags of varying fineness and silica fume on the consistency, temperature rise, and strength development. It was found that, from an overall point of view, a blend of cement, slag, and silica fume in proportions of 2:7:1, using a slag with 6000 cm²/g by Blaine, yields the best result. Concrete specimens were then cast in the second phase, using the mix of cement just mentioned, and it was verified that the temperature rise could be brought down by as much as 30 C without adversely affecting the strength at 91 days (about 80 Mpa), though the early age strength was slightly lower.

Engineered enchancement of or engineered alternatives to shallow land disposal of low-level radioactive (LLW) is likely to be the disposal technique adopted by a majority of states in the U.S. Such disposal techniques involve extensive use of concrete as an engineered barrier to prevent the escape of radionuclides into the environment. The LLW will be contained in concrete vaults or bunkers buried underground or covered with earth. U.S. Regulation 10 CFR 61 establishes the regulatory responsibilities for licensing LLW disposal sites. Implicit in the regulations is the need for the concrete of the LLW disposal system to have a service life of 500 years. Discusses the regulatory responsibilities governing LLW disposal. It also discusses results of a research project at the National Institute of Standards and Technology for the U.S. Nuclear Regulatory Commission to predict the service life of underground concrete for LLW applications. Assuming that disposal will be above the water table, the major degradation mechanisms affecting the concrete would be those due to sulfate attack, chloride ions, alkali-aggregate reaction, and leaching. Mathematical modeling of the degradation mechanisms and the validation of those models with accelerated laboratory tests suggests that service lives of 500 years for concrete structures can be reliably achieved.

Three of the major uses of silica fume (microsilica) additions to concrete have been to improve mechanical properties, improve corrosion resistance by reducing permeability to aggressive anions such as chlorides, and improve concrete resistance to chemical degradation. In the last two uses, the mechanical properties are also enhanced beyond those of ordinary portland cement concretes of the same mix proportions without silica fume. Thus, the production of durable concrete often leads to an improvement in mechanical properties. Long-term resistance in accelerated laboratory corrosion testing in sodium chloride solutions is documented. It is shown that silica fume significantly lowers chloride ingress with increasing efficiency as the water-cementitious ratio decreases. A clear improvement in corrosion performance with the addition of calcium nitrite corrosion inhibitor became evident in this long-term program. It is also documented that high concrete resistivities do not necessarily prevent severe corrosion from occurring. Chemical resistance of silica fume (microsilica) concretes to numerous acids, bases, and salts is also examined. The results show significant improvements with the addition of silica fume in the time to 25 percent mass loss in cyclic and continuous ponding experiments for most chemicals. For some highly alkaline solutions, there is no improvement with microsilica. Improvements in compressive strength are documented for the mixtures used in the corrosion and chemical resistance studies. Additional mixtures were examined to determine flexural strength and modulus of elasticity. These mixtures were similar in composition to those typically used for corrosion protection. The results showed that silica fume significantly increased strengths and the modulus of elasticity. The improvement in flexural strength was greater than that expected from formulas typically used for moderate strength concretes and the increase in modulus of elasticity was less. It is hoped that the design engineer will be able to utilize the data to take full advantage of the property improvements and not merely durability or strength improvements with silica fume.

The durability of alkali-resistant glass fiber in cement matrixes with and without silica fume was investigated. Several attack modes such as hydroxylation, mass dissolution, and notching by calcium hydroxide crystals were distinguished. The effect of silica fume addition was found to be slight; it greatly reduced the calcium hydroxide content of the cement matrix and inhibited notching attack, but it did not reduce the internal pH sufficiently to inhibit hydroxylation and mass dissolution. The flexural strength of cement pastes at 20 C with and without silica fume initially increased during the first month and thereafter started to decrease and eventually leveled off at longer ages. The addition of silica fume gave only a marginal improvement to the elastic properties of composites at 20 C. At 55 C, the flexural strengths of both formulations were observed to decrease very rapidly, approaching the flexural strength of the unreinforced matrix.