International Concrete Abstracts Portal

This paper gives the results of an investigation on the performance of high-volume fly ash concrete made with ASTM Class F fly ashes from three different sources. Cementitious materials contents of 300, 370, and 430 kg/m3 were used. The percentage of fly ash used was 58 percent of the total cementitious materials content. All the concrete mixtures were air-entrained and superplasticized. A large number of concrete specimens were subjected to the determination of compressive and flexural strengths, Young's modulus of elasticity, creep strain, drying shrinkage, abrasion resistance, deicing salt-scaling resistance, and resistance to chloride-ion penetration. High-volume fly ash concrete with adequate early-age strengths and excellent later age strengths can be produced with cement and total cementitious materials as low as 125 and 300 kg/m3, respectively. The Young's modulus of elasticity, creep, and drying shrinkage of high-volume concrete are comparable to those of the plain portland cement concrete. The high-volume fly ash concrete shows excellent resistance to chloride-ion penetration and outperforms plain portland cement concrete. The total charge in coloumbs at 91 days, a measure of resistance to the chloride-ion penetration, ranges from 278 to 1078. The corresponding values for reference concrete range from 1003 to 2313. Further research is needed to explain the relatively poor performance of the high-volume fly ash concrete under deicing salt scaling and abrasion tests.

Describes the basic properties of concrete containing ultrafine particles, which are produced from fly ash. The ultrafine particles are produced from fly ash with ultra-high temperature treatment. This treatment enables control of the specific surface area, from 20 to 130 mý/g, by controlling the quenching speed. The main chemical component is SiO2, over 60 percent of which is amorphous. Ignition loss, which is 1 to 5 percent with fly ash, is below 0.2 percent. The properties of concrete with these ultrafine particles differ greatly in the specific surface area of the particles. Experiments showed that ultrafine particles with a specific surface area of 71 mý/g develop a compressive strength of approximately 118 MPa (w/c = 25 percent), while plain concrete develops approximately 105 MPa. Ultrafine particles with a specific surface area of 35 mý/g improve the consistency of fresh concrete, especially in a low water/cement (w/c = 20 to 25 percent), enabling concrete to be easily mixed without increasing the dosage of high-range air-entraining (AE) water reducer. Results show ultrafine particles to be highly active and useful as an admix material for high strength concrete.

29Si NMR has been employed as a tool to characterize the reaction mechanism of hydration in several blended cements up to 6 to 9.5 months. The cements investigated were blends with silica fume, fly ash, activated kaolinite, and blast furnace slag. Spectra deconvolution indicated that, in the silica fume as well as in the activated kaolinite blend, the reaction of the anhydrous calcium-silicates is initially accelerated with respect to the ordinary portland cement. In the fly ash blends, this effect is smaller. Both in the silica fume and fly ash blends, an increase in the amount of silica middle groups (Qý-type) at - 84 ppm, relative to the amount of silica end groups (Q1-type) at - 79 ppm, is notable, which indicates an increased tendency to form longer CSH chains. The size distribution and glass content of the fly ashes used seem to influence the hydration reaction, which is reflected by somewhat higher Qý/Qý ratios and an increased initial hydration. In the blends with activated kaolinite, it was not possible to deconvolute the Q1 and Qý chemical shifts at all ages, due to changes in the shift maxima Q1 and/or Qý. This may be due to the formation of amorphous noncrystalline alumina-containing reaction products. The chemical shift of the blast furnace slag appeared too broad for a successful deconvolution. In general, both the total (Q1 + Qý) as well as the Qý/Q1 ratio correlate with compressive strength data, Qý species contributing markedly. Paper contains a general overview of the application of NMR spectroscopy in cement and concrete research.

The lining of underground cavities for storage of natural gas requires a proper cementing paste as does the cementing of casing in boreholes placed in salt beds. The following properties of the cementing pastes are required: high corrosion resistance, minimal shrinkage, even some expansion, high leak tightness, good bond to steel and rock, proper rheology and strength. The following blended cements were investigated: cement "Nowa Huta" 25 with 40% blast-furnace slag (bfs), cement "Rejowiec" 45 for bridge construction and cement with 70% bfs. The cements were mixed with NaCl brine at a concentration 310 g NaCl/L at liquid to solid ration 0.45. The properties of pastes, such as density, rheological, sedimentation and filtration characteristics; time of setting; strength development and shrinkage were determined. The phase composition of pastes was studied by XRD and the microstructure was observed under SEM. The best results were obtained for the pastes with the blast-furnace slag.

The resistance to freezing-and-thawing and chloride diffusion of antiwashout underwater concrete was investigated to evaluate the applicability for tidal zone in cold districts or reinforced concrete structures in marine environments. Comparisons were made with ordinary portland cement concrete of similar mix design. Two types of cement (ordinary portland cement and portland blast furnace slag cement) were used. Two types of blast furnace slag (Blaine fineness 500 and 700 m²/kg) were used as a cement replacement (slag content 30 and 50 percent by weight). The results show that antiwashout underwater concrete without blast furnace slag shows poor resistance to freezing-and-thawing compared with normal concrete. But the freezing-and-thawing resistance can be improved with blast furnace slag. This is due to the fact that concrete containing blast furnace slag has dense pore structures. Pore volume in the range of 10 to 10 3 nm in radius decreases significantly with blast furnace slag. Similarly, chloride diffusion depth becomes smaller with blast furnace slag.