The service conditions for concrete construction in the coastal areas of the Arabian Gulf are considered to be those of one of the most aggressive environments in the world. Deterioration of hardened cement paste due to salt attack is one of the leading reasons for poor performance of concrete structures in this region. Calcium, magnesium, sodium salts of sulfates, chlorides, and carbonates extensively contaminate the ground, groundwater, and the aggregates. In such an environment, structures built with concrete which can be rated as good in temperate climatic conditions can hardly last for a decade or two. Field and laboratory studies are in progress at King Fahd University of Petroleum and Minerals at Dhahran, Saudi Arabia, to formulate preventive measures. As a part of this endeavor, the performance of in-service concrete structures is monitored. This paper details the investigations carried out to evaluate the performance of these concrete structures. Data developed in this investigation show that the aggressive service environment is the major cause for concrete deterioration, as such appropriate mix design techniques and construction practices are to be adopted for the production of a very dense and impermeable concrete.

Twenty-seven high-performance concrete mixes (with 28-day strengths in the 80 to 100 MPa range) were prepared to evaluate the deicer salt scaling resistance of such concretes after various periods of curing. Three water-cement ratios (0:30, 0:26, and 0:23) were used, and for each water-cement ratio a minimum of three mixes were made with different air-void systems: one with a spacing factor of approximately 200 æ, one with a slightly higher value, and one without any air entrainment. Canadian Type 30 cement with an addition of 6 percent silica fume was used for all mixes. The coarse aggregate was a 14 mm minimum size, crushed, very dense, dolomitic limestone. The curing period varied between 1 and 28 days. A total of 54 specimens (2 for each test condition) were submitted to 150 daily cycles in accordance with ASTM Standard C 672, using sodium chloride as a deicer. Weight loss was measured to evaluate the deterioration of the concrete surfaces. The scaling resistance was found to be extremely good in all cases, irrespective of the length of curing, water-cement ratio, or spacing factor value, weight losses after 150 cycles being always lower than 0.50 kg/mý. No correlation was found between the scaling resistance and the spacing factor or the length of curing. Loss of mass was generally concentrated around a few aggregate particles. These results indicate clearly that it is possible to prepare high-performance concretes with very good deicer salt scaling resistance without using any air entrainment.

The air or oxygen permeability of concrete is usually measured by means of techniques that utilize mechanical driving forces. Thus, air or oxygen is forced to pass through a piece of concrete using different mechanical pressures. The flow of gas so measured is used as an indication of concrete permeability and sometimes is also used to predict the durability of concrete reinforcements based on the relationship between anodic corrosion rate and amount of oxygen, which may be reduced in the cathodic areas. However, this extrapolation may lead to erroneous conclusions, because a dry concrete allows a higher amount of oxygen to pass through it than a wet one, although the corrosion rate should be much lower in dry than in wet concrete. In this paper, comparisons between flow of oxygen measured in paste, mortar, and concrete specimens held at different relative humidities using electrochemical driving forces (polarization at about -750 mV SCE), and corrosion rates (measured by means of polarization resistance) are presented to discuss the inherent relationships. The results show that the oxygen permeability is only dependent on the amount of electrolyte inside the pores, but the corrosion rate is also dependent on the concrete resistivity, which is fixed by the amount of pore water content.

Concrete will be immune to the effects of freezing and thawing if: 1) it is not in an environment where freezing and thawing take place, i.e., where freezable water may be present in the concrete; 2) there are no pores in the concrete large enough to hold freezable water when freezing takes place (i.e., no capillary cavities); 3) during freezing of freezable water, the pores containing freezable water are never more than 91 percent filled, i.e., not critically saturated; 4) during freezing of freezable water, the pores containing freezable water are more than 91 percent full and the paste has an air-void system with an air bubble located not more than 0.2 mm (0.008 in.) from anywhere (L ó 0.2 mm), sound aggregate, and moderate maturity. Sound aggregate is aggregate that does not contain significant amounts of accessible capillary pore space that is likely to be critically saturated when freezing occurs. The way to establish that such is the case is to subject properly air-entrained, properly mature concrete, made with the aggregate in question, to an appropriate laboratory freeze-thaw test, such as ASTM C 666, Procedure A. Moderate maturity means that the original mixing water-filled space has been reduced by cement hydration so that the remaining capillary porosity that can hold freezable water is a small enough fractional volume of the paste so that the expansion of the water on freezing can be accommodated by the air-void system.

The No. 1 ore dock at Great Lakes Steel Division's Zug Island facility was originally constructed in 1909. Damage caused by freeze-thaw cycling, abrasion wear, severe impact loadings, and reinforcing steel corrosion resulted in a need for repair and rehabilitation. Multiple Dynamics Corporation conducted extensive condition surveys and testing to develop repair strategies for this structure. The remaining service life was then predicted to assist in economic planning. This case history provides an excellent example of concrete performance in an aggressive environment.