Circulating Fluidized Bed Combustion Fly-Ash-Activated Slag Concrete as Novel Construction Material

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Title: Circulating Fluidized Bed Combustion Fly-Ash-Activated Slag Concrete as Novel Construction Material

Author(s): Nguyen Tien Dung, Ta-Peng Chang, and Chun-Tao Chen

Publication: Materials Journal

Volume: 112

Issue: 1

Appears on pages(s): 105-114

Keywords: CFBC fly ash; drying shrinkage; hydration product; modulus of elasticity; slag; ultrasonic pulse velocity

DOI: 10.14359/51686910

Date: 1/1/2015

Abstract:
The performance of a novel concrete made with an eco-binder, referred to as SCA binder, that only contains raw slag (S) and raw circulating fluidized bed combustion (CFBC) fly ash (CA) without ordinary portland cement was evaluated. The major hydration products of SCA binders are ettringite, C-S-H, and C-A-S-H, which lead to SCA pastes with proper setting times, dense microstructures, and high compressive strengths up to approximately 80 MPa (11,600 psi). The SCA concrete, which is suitable for practical applications, has compressive and tensile strengths at 91 days of approximately 50 MPa (7250 psi) and nearly 5 MPa (725 psi), respectively. In addition, the SCA concrete shows moderate expansion at early ages and a low rate of shrinkage after 91 days of exposure. The regression equations that relate the splitting tensile strength, modulus of elasticity, and ultrasonic pulse velocity to the compressive strength are presented with a satisfactory coefficient of determination.

Related References:

1. Hannesson, G.; Kuder, K.; Shogren, R.; and Lehman, D., “The Influence of High Volume of Fly Ash and Slag on the Compressive Strength of Self-Consolidating Concrete,” Construction and Building Materials, V. 30, May 2012, pp. 161-168. doi: 10.1016/j.conbuildmat.2011.11.046

2. Kuder, K.; Lehman, D.; Berman, J.; Hannesson, G.; and Shogren, R., “Mechanical Properties of Self Consolidating Concrete Blended with High Volumes of Fly Ash and Slag,” Construction and Building Materials, V. 34, Sept. 2012, pp. 285-295. doi: 10.1016/j.conbuildmat.2012.02.034

3. Hardjito, D.; Wallah, S. E.; Sumajouw, D. M. J.; and Rangan, B. V., “On the Development of Fly Ash-Based Geopolymer Concrete,” ACI Materials Journal, V. 101, No. 6, Nov.-Dec. 2004, pp. 467-472.

4. Berry, M.; Stephens, J.; and Cross, D., “Performance of 100% Fly Ash Concrete with Recycled Glass Aggregate,” ACI Materials Journal, V. 108, No. 4, July-Aug. 2011, pp. 378-384.

5. Li, X.-G.; Chen, Q.-B.; Huang, K.-Z.; Ma, B.-G.; and Wu, B., “Cementitious Properties and Hydration Mechanism of Circulating Fluidized Bed Combustion (CFBC) Desulfurization Ashes,” Construction and Building Materials, V. 36, Nov. 2012, pp. 182-187. doi: 10.1016/j.conbuildmat.2012.05.017

6. Iribarne, J.; Iribarne, A.; Blondin, J.; and Anthony, E. J., “Hydration of Combustion Ashes—A Chemical and Physical Study,” Fuel, V. 80, No. 6, 2001, pp. 773-784. doi: 10.1016/S0016-2361(00)00158-7

7. Jackson, N. M.; Schultz, S.; Sander, P.; and Schopp, L., “Beneficial Use of CFB Ash in Pavement Construction Applications,” Fuel, V. 88, No. 7, 2009, pp. 1210-1215. doi: 10.1016/j.fuel.2008.04.031

8. Glinicki, M., and Zielinski, M., “Frost Salt Scaling Resistance of Concrete Containing CFBC Fly Ash,” Materials and Structures, V. 42, No. 7, 2009, pp. 993-1002. doi: 10.1617/s11527-008-9438-y

9. Shon, C.-S.; Mukhopadhyay, A. K.; Saylak, D.; Zollinger, D. G.; and Mejeoumov, G. G., “Potential Use of Stockpiled Circulating Fluidized Bed Combustion Ashes in Controlled Low Strength Material (CLSM) Mixture,” Construction & Building Materials, V. 24, No. 5, 2010, pp. 839-847. doi: 10.1016/j.conbuildmat.2009.10.022

10. Ghafoori, N., and Mora, C. A. G., “Compacted Non-Cement Concrete Utilizing Fluidized Bed and Pulverized Coal Combustion By-Products,” ACI Materials Journal, V. 95, No. 5, Sept.-Oct. 1998, pp. 582-592.

11. Li, X.-G.; Chen, Q.-B.; Ma, B.-G.; Huang, J.; Jian, S.-W.; and Wu, B., “Utilization of Modified CFBC Desulfurization Ash as an Admixture in Blended Cements: Physico-Mechanical and Hydration Characteristics,” Fuel, V. 102, Dec, 2012, pp. 674-680. doi: 10.1016/j.fuel.2012.07.010

12. Sheng, G.; Li, Q.; Zhai, J.; and Li, F., “Self-Cementitious Properties of Fly Ashes from CFBC Boilers Co-Firing Coal and High-Sulphur Petroleum Coke,” Cement and Concrete Research, V. 37, No. 6, 2007, pp. 871-876. doi: 10.1016/j.cemconres.2007.03.013

13. Oberlink, A. E., “Non-Portland Cement Activation of Blast Furnace Slag,” master’s thesis, University of Kentucky, Lexington, KY, 2010, 69 pp.

14. Palacios, M., and Puertas, F., “Effectiveness of Mixing Time on Hardened Properties of Waterglass-Activated Slag Pastes and Mortars,” ACI Materials Journal, V. 108, No. 1, Jan.-Feb. 2011, pp. 73-78.

15. ACI Committee 211, “Standard Practice for Selecting Proportions for Normal, Heavyweight, and Mass Concrete (ACI 211.1-91) (Reapproved 2002),” American Concrete Institute, Farmington Hills, MI, 1991, 38 pp.

16. ASTM C230/C230M, “Standard Specification for Flow Table for Use in Tests of Hydraulic Cement,” ASTM International, West Conshohocken, PA, 2008, 6 pp.

17. ASTM C191-07, “Standard Test Methods for Time of Setting of Hydraulic Cement by Vicat Needle,” ASTM International, West Conshohocken, PA, 2007, 8 pp.

18. ASTM C109/C109M-99, “Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens),” ASTM International, West Conshohocken, PA, 1999, 6 pp.

19. ASTM C143/C143M-12, “Standard Test Method for Slump of Hydraulic-Cement Concrete,” ASTM International, West Conshohocken, PA, 2012, 4 pp.

20. ASTM C39/C39M-99, “Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens,” ASTM International, West Conshohocken, PA, 1999, 5 pp.

21. ASTM C496-96, “Standard Test Method for Splitting Tensile Strength of Cylindrical Concrete Specimens,” ASTM International, West Conshohocken, PA, 1996, 4 pp.

22. ASTM C215-97e1, “Standard Test Method for Fundamental Transverse, Longitudinal, and Torsional Resonant Frequencies of Concrete Specimens,” ASTM International, West Conshohocken, PA, 1997, 6 pp.

23. ASTM C597-09, “Standard Test Method for Pulse Velocity Through Concrete,” ASTM International, West Conshohocken, PA, 2009, 4 pp.

24. ASTM C157/C157M-99, “Standard Test Method for Length Change of Hardened Hydraulic-Cement Mortar and Concrete,” ASTM International, West Conshohocken, PA, 1999, 7 pp.

25. Brandštetr, J.; Havlica, J.; and Odler, I., “Properties and Use of Solid Residue from Fluidized Bed Coal Combustion,” Waste Materials Used in Concrete Manufacturing, C. Satish, ed., William Andrew Publishing, Westwood, NJ, 1996, pp. 1-52.

26. Wang, J.; Wu, Y.; and Anthony, E. J., “The Hydration Behavior of Partially Sulfated Fluidized Bed Combustor Sorbent,” Industrial & Engineering Chemistry Research, V. 44, No. 22, 2005, pp. 8199-8204. doi: 10.1021/ie0507124

27. Mindess, A.; Young, J. F.; and Darwin, D., Concrete, second edition, Prentice Hall, Upper Saddle River, NJ, 2003, 644 pp.

28. Singh, N. B.; Sarvahi, R.; and Singh, N. P., “Effect of Superplasticizers on the Hydration of Cement,” Cement and Concrete Research, V. 22, No. 5, 1992, pp. 725-735. doi: 10.1016/0008-8846(92)90095-D

29. Song, S., and Jennings, H. M., “Pore Solution Chemistry of Alkali-Activated Ground Granulated Blast-Furnace Slag,” Cement and Concrete Research, V. 29, No. 2, 1999, pp. 159-170. doi: 10.1016/S0008-8846(98)00212-9

30. Sheng, G.; Li, Q.; and Zhai, J., “Investigation on the Hydration of CFBC Fly Ash,” Fuel, V. 98, 2012, pp. 61-66. doi: 10.1016/j.fuel.2012.02.008

31. Álvarez-Ayuso, E., and Nugteren, H. W., “Synthesis of Ettringite: A Way to Deal with the Acid Wastewaters of Aluminium Anodising Industry,” Water Research, V. 39, No. 1, 2005, pp. 65-72. doi: 10.1016/j.watres.2004.07.029

32. Taylor, H. F. W., “Nanostructure of C-S-H: Current Status,” Advanced Cement Based Materials, V. 1, No. 1, 1993, pp. 38-46. doi: 10.1016/1065-7355(93)90006-A

33. Lin, Y.; Kuo, S.-F.; Hsiao, C.; and Lai, C.-P., “Investigation of Pulse Velocity-Strength Relationship of Hardened Concrete,” ACI Materials Journal, V. 104, No. 4, July-Aug. 2007, pp. 344-350.


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