Industrially produced mechanochemically activated clay - the first of its kind

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Title: Industrially produced mechanochemically activated clay - the first of its kind

Author(s): T. Neumann, M. Fylak, A. Hamm, O. Maier, H. Möller

Publication: Symposium Paper

Volume: 370

Issue:

Appears on pages(s): 147-154

Keywords: mechanochemical activation, clay, sustainable cement, agitator bead mill, strength activity index (SAI), LC3 cement, Allmeca

DOI: 10.14359/51751756

Date: 5/1/2026

Abstract:
The mitigation of CO₂ emissions in cement production increasingly relies on alternative cementitious materials (SCMs), given the declining availability of traditional sources such as blast furnace slag and fly ash. This study examines the mechanochemical activation of clays as a low-carbon alternative to thermal calcination. Mechanochemical activation - implemented through high-energy dry grinding in an industrial agitated bead mill - induces pronounced structural modifications in clay minerals and enhances their pozzolanic reactivity. Experimental results indicate a lower demand for superplasticizers and accelerated early strength development in cementitious systems incorporating mechanochemically activated clays. The first industrial-scale application at the SCHWENK plant in Allmendingen (Allmeca) demonstrates the scalability of this process, which utilizes locally sourced clays and ensures consistent activation performance. Furthermore, the integration of activated clays with limestone powder, aligned with the LC3 concept, significantly improves both workability and concrete strength. This approach provides a sustainable pathway for cement production that leverages regional resources while reducing environmental impact.

Related References:

1. Juhász A. Z., Opoczky L. (1990) “Mechanical activation of minerals by grinding, pulverizing, and morphology of particles.” 1st edition, Ellis Horwood Limited, England. ISBN 0-7458-0015-7

2. Tole, I.; et al. “Mechanochemical activation of natural clay minerals: an alternative to produce sustainable cementitious binders – review.” Mineralogy and Petrology (2019) 113: pp. 449-462

3. Amroun, S. et al “Mechanochemical activation of basaltic fines.” Cement and Concrete Research 195 (2025) 107923

4. Schmidt, W.; et. al. “Pressure as the driving force for mechanochemical reactions on the example of ion metathesis of alkali halides upon ball milling.” Royal Society of Chemistry. 12/2024. doi: 10.1039/d4mr00104d

5. Baki, V. A.; et al. “The impact of mechanochemical activation on the physicochemical properties and pozzolanic reactivity of Kaolinite, muscovite, and montmorillonite.” Cement and Concrete Research 162 (2022). 106962

6. Yao, G.; et al. “Pozzolanic activity and hydration properties of feldspar after mechanical activation.” Powder Technology 383 (2021). pp. 167–174

7. Tole, I.; et al. “Enhancement of the puzzolanic activity of natural clays by mechanochemical activation.” Construction and Building Materials 352 (2022). 128739

8. Plusquellec, G.; et al. “Refinement of activation methods for increased reactivity of kaolinitic and illitic clays.” 16th Int. Conf. on Chemistry of Cement and Concrete. 2023. Bangkok

9. Fitos, M.; et al. “Pozzolanic activity of thermally and mechanically treated kaolins of hydrothermal origin.” Applied Clay Science. 20215. pp. 116-117