Mitigation of Microcracking in Alkali-Activated Combined Slag and Fly Ash Concretes for Good Performance in Winter Conditions

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Title: Mitigation of Microcracking in Alkali-Activated Combined Slag and Fly Ash Concretes for Good Performance in Winter Conditions

Author(s): Alexandre Rodrigue, Josée Duchesne, Benoit Fournier and Benoit Bissonnette

Publication: Symposium Paper

Volume: 320

Issue:

Appears on pages(s):

Keywords: Alkali-activated concrete; autogenous shrinkage; cracking

DOI: 10.14359/51701046

Date: 8/1/2017

Abstract:
Concerns regarding the higher shrinkage and early cracking of alkali-activated binders can become a major issue for resistance to de-icing salts scaling, freeze-thaw cycles and/or chemical attacks. Using the Damage Rating Index (DRI) method, cracking has been quantified in concrete samples using a slag/fly ash binder activated with a combined sodium hydroxide and sodium silicate solution. The decrease of the added water dosage and the fly ash content results in an increase in the DRI values in the presence of slag/fly ash binder. Alkali-activated pastes with the same binding phase characteristics were tested using the ASTM C1698 for the evaluation of the autogenous volume changes to explain the observed cracking. With a constant activator-to-binder ratio of 0.35, different added water-to-binder ratios (0.12, 0.14 and 0.16) and fly ash contents (20, 30, and 40 %) were investigated. Autogenous shrinkage was found to decrease with increasing water dosage and fly ash content.

Related References:

1. Barcelo, L., Kline, J., Walenta, G. & Gartner, E. Cement and carbon emissions. Mater. Struct. 47, 2013, pp. 1055–1065.

2. Lee, N. K., Jang, J. G. & Lee, H. K. Cement & Concrete Composites Shrinkage characteristics of alkali-activated fly ash / slag paste and mortar at early ages. Cem. Concr. Compos. 53, 2014, pp. 239–248.

3. Ma, Y. & Ye, G. Cement and Concrete Research The shrinkage of alkali activated fl y ash., Cement and Concrete Research, 68, 2015, pp. 75–82.

4. Duran Atis, C., Bilim, C., Çelik, Ö. & Karahan, O. Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar. Constr. Build. Mater. 23, 2009, pp. 548–555.

5. Melo Neto, A. A., Cincotto, M. A. & Repette, W. Drying and autogenous shrinkage of pastes and mortars with activated slag cement. Cem. Concr. Res. 38, 2008, pp. 565–574.

6. Duxson, P., Fernandez-Jimenez, A., Provis, J. L., Lukey, G. C., Palomo, A. & van Deventer, J. S. J. Geopolymer technology: The current state of the art. J. Mater. Sci. 42, 2007, pp. 2917–2933.

7. Palomo, a., Grutzeck, M. W. & Blanco, M. T. Alkali-activated fly ashes: A cement for the future. Cem. Concr. Res. 29, 1999, pp. 1323–1329.

8. Richardson, I. G., Brough, a. R., Groves, G. W. & Dobson, C. M. The characterization of hardened alkali-activated blast-furnace slag pastes and the nature of the calcium silicate hydrate (C-S-H) phase. Cem. Concr. Res. 24, 1994, pp. 813–829.

9. Myers, R. J., Bernal, S. a., San Nicolas, R. & Provis, J. L. Generalized structural description of calcium-sodium aluminosilicate hydrate gels: The cross-linked substituted tobermorite model. Langmuir 29, 2013, pp. 5294–5306.

10. Puertas, F., Palacios, M., Manzano, H., Dolado, J. S., Rico, A. & Rodriguez, J. A model for the C-A-S-H gel formed in alkali-activated slag cements. J. Eur. Ceram. Soc. 31, 2011, pp. 2043–2056.

11. Bernal, S. A., Provis, J. L., Walkley, B., San Nicolas, R., Gehman, J. D., Brice, D. G., Kilcullen, A. R., Duxson, P. & van Deventer, J. S. J. Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation. Cem. Concr. Res. 53, 2013, pp. 127–144.

12. Provis, J. L., Myers, R. J., White, C. E., Rose, V. & Van Deventer, J. S. J. X-ray microtomography shows pore structure and tortuosity in alkali-activated binders. Cem. Concr. Res. 42, 2012, pp. 855–864.

13. Yao, X., Yang, T. & Zhang, Z. Compressive strength development and shrinkage of alkali-activated fly ash–slag blends associated with efflorescence. Mater. Struct. 49, 2016, pp. 2907–2918.

14. Gao, X., Yu, Q. L. & Brouwers, H. J. H. Assessing the porosity and shrinkage of alkali activated slag-fly ash composites designed applying a packing model. Constr. Build. Mater. 119, 2016, pp. 175–184.

15. ASTM Standard C1698. Test Method for Autogenous Strain of Cement Paste and Mortar., ASTM Int., 2014, pp. 1–8.

16. ASTM Standard C305, Standard Practice for Mechanical Mixing of Hydraulic Cement Pastes and Mortars of Plastic Consistency, ASTM Int., 2014, pp. 1–3.

17. Canadian Standards Association. A23.1-09 Concrete Materials and Methods of Concrete Construction / Test Methods and Standard Practices for Concrete., 2011.

18. Villeneuve, V., Fournier, B. & Duchesne, J. Determination of the damage in concrete affected by ASR- the damage rating index (DRI). Proc. 14th Int. Conf. Alkali-Aggregate React. Concr., 2012, 10 pp.

19. Fournier, B., Fecteau, P.-L., Villeneuve, V., Tremblay, S. & Sanchez, L. F. M. Description of petrographic features of damage in concrete used in the determination of the damage rating index (DRI). 2015, 58 pp.

20. ASTM Standard C191. Standard Test Method for Time of Setting of Hydraulic Cement by Vicat Needle. ASTM Int. i, 2013, pp. 1–8.

21. Montgomery, D. C. Applied Statistics and Probability for Engineers Third Edition. John Wiley & Sons, Inc., Phoenix Usa 37, 2003, 976 pp.

22. Noushini, A. & Castel, A. The effect of heat-curing on transport properties of low-calcium fly ash-based geopolymer concrete. Constr. Build. Mater. 112, 464–477 (2016).